有机化学 ›› 1991, Vol. 11 ›› Issue (2): 182-187. 上一篇    下一篇

研究论文

一类新型的"三块板"式卟啉化合物的合成及光物理性质初探

郭础;尹春凤;谢虹   

  1. 北京理工大学;河北师范学院
  • 发布日期:1991-04-25

The synthesis of novel trilaminated type porphyrins and a primary exploration of their spectral characteristics

GUO CHU;YIN CHUNFENG;XIE HONG   

  • Published:1991-04-25

本文研究了一类新型的"三块板"式卟啉化合物的合成及它们的光物理性质。

关键词: 紫外分光光度法, 荧光分光光度法, 红外分光光度法, 元素分析, 核磁共振谱法, 质谱法, 物理光学, 卟啉

Four novel trilaminated type porphyrins I (R = H, o-, m- p-NO2) are synthesized and their structures are demonstrated by UV, IR, 1H NMR, MS and elemental anal. Their spectral characteristics are investigated and the results obtained reveal that intramol. electron transfer is related with their conformation and their environment.

Key words: INFRARED SPECTROPHOTOMETRY, ULTRAVIOLET SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, FLUOROSPECTROPHOTOMETRY, NMR SPECTROMETRY, MASS SPECTROGRAPHY, PHYSICAL OPTICS, PORPHYRIN

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