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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (07): 815-819. 上一篇    下一篇

研究论文

含硫—硫键的新型苯胺类化合物的合成

邓仕任1，胡高强1，鄢勇1，郭建平2，黄伟国2
周运鸿1，李早英*,1   

  1. (1武汉大学化学与分子科学学院 武汉 430072)
    (2香港浸会大学化学系 香港 九龙塘)
  • 收稿日期:2004-10-19 修回日期:2005-02-17 发布日期:2005-06-30
  • 通讯作者: 李早英

A New Synthetic Route of Disulfide Containing Aniline Compounds

DENG Shi-Ren1,HU Gao-Qiang1,YAN Yong1,GUO Jian-Ping2
HUANG Wei-Guo2,ZHOU Yun-Hong1,LI Zao-Ying*,1   

  1. (1 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072)
    (2 Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong)
  • Received:2004-10-19 Revised:2005-02-17 Published:2005-06-30
  • Contact: LI Zao-Ying

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2655

被引次数

3

通过一条新的合成路线得到了一个已知化合物5-氨基-1,4-二氢苯唑并[d]-1',2'-二硫因(1). 同时成功地合成了一个新的类似化合物9-氨基-1,2,3,4,5,6,7,8-八氢-2,3,6,7-四硫代蒽(2). 目标化合物及其中间体的结构经1H, 13C NMR, MS, IR确证, X单晶衍射测定了化合物9-硝基-1,2,3,4,5,6,7,8-八氢-2,3,6,7-四硫代蒽(10)的结构.

关键词: 二硫化合物, 苯胺, 单晶分析

A new route was employed to synthesize a known compound, 5-amino-1,4-dihydro- benzo[d]-1',2'-dithiadiene (1), and a new analogue, 9-amino-1,2,3,4,5,6,7,8-octahydro-2,3,6,7-tetrathianthracene (2) was successfully synthesized fol-lowing this method. The structures of target compounds and their intermediates have been characterized by 1H, 13C NMR, MS spectra and the structure of 9-nitro- 1,2,3,4,5,6,7,8-octahydro-2,3,6,7-tetrathianthracene (10) was determined by X-ray single crystal analysis.

Key words: aniline, disulfide, single crystal analysis