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有机化学
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有机化学 ›› 1995, Vol. 15 ›› Issue (1): 57-60. 上一篇    下一篇

研究论文

1-硫代-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷基-4-亚甲基硫醚及其亚砜的合成

李玉桂;王新龙;朱雪峰;周汉杰   

  1. 南开大学元素有机化学研究所
  • 发布日期:1995-02-25

Study on the synthesis of 1-sulfur-1-phospha-2,6, 7-trioxzbicyclo [2.2.2] octyl-4-methyl thioethers and its sulfoxides

LI YUGUI;WANG XINLONG;ZHU XUEFENG;ZHOU HANJIE   

  • Published:1995-02-25

被引次数

13

本文通过Williamson反应, 合成了9个双环笼状硫代磷酸酯的硫醚衍生物3a～i. 以3b,3c为例研究了硫醚衍生物的还原性, 并合成相应的亚砜化合物4b,4c. 讨论了亚砜化合物的立体化学.

关键词: 合成, 亚砜, 硫醚, 双环磷酸酯类化合物

Nine new thioethers of caged bicyclic thiophosphates 3a～i were propared by Williamson reaction. Oxidation of the thioethers 3b and 3c gave the corresponding sulfoxide 4b and 4c which containning one chiral sulfur atom. The stereochemistry of the slfoxide was also discussed.

Key words: SULFOXIDE, SULFUR ETHER, SYNTHESIS, BICYCLIC PHOSPHATES

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