有机化学 ›› 1995, Vol. 15 ›› Issue (1): 64-67. 上一篇    下一篇

研究论文

"一锅法"简便合成一芳基硼酸和二芳基硼酸

黄世文;单自兴;赵德杰   

  1. 武汉大学化学系
  • 发布日期:1995-02-25

A simple and convenient preparation of aryl boronic and diaryl borinic acids by one-pot grignard reaction

HUANG SHIWEN;SHAN ZIXING;ZHAO DEJIE   

  • Published:1995-02-25

本文改进了一芳基硼酸和二芳基硼酸的制备方法. 利用芳卤, 镁屑, 硼酸三正丁酯或三氟化硼乙醚溶液在室温下"一锅"反应简便合成一芳基硼酸和二芳基硼酸, 分离产率为48~80% .

关键词: 格氏反应, 芳基硼酸, 一锅法

A simple and convenient method for the preparation of aryl boronic and diaryl borinic acids was developed based on a one-pot reaction between arylhalide, magnesium and tributyl borate or boron trifluoride etherate at room temperature.

Key words: GRIGNARD REACTION

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