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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (05): 782-790. 上一篇    下一篇

综述与进展

缩醛化反应研究进展

申艳霞a，江焕峰*,a，汪朝阳a,b   

  1. (a华南理工大学化学科学学院 广州 510640)
    (b华南师范大学化学系 广州 510631)
  • 收稿日期:2006-03-07 修回日期:2007-10-09 发布日期:2008-05-20
  • 通讯作者: 江焕峰

Research Progress in Acetalization

SHEN Yan-Xiaa,JIANG Huan-Feng*,a,WANG Zhao-Yanga,b   

  1. (a College of Chemistry, South China University of Technology, Guangzhou 510640)
    (b Department of Chemistry, South China Normal University, Guangzhou 510631)
  • Received:2006-03-07 Revised:2007-10-09 Published:2008-05-20
  • Contact: JIANG Huan-Feng

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5716

被引次数

43

缩醛化合物是非常重要的有机合成中间体. 介绍了以醛、烯烃为原料合成缩醛化合物的方法以及这两类合成方法研究的最新进展, 尤其介绍了在合成缩醛化合物方面开发的新型绿色催化剂、绿色新技术与绿色工艺.

关键词: 缩醛化反应, 绿色化学, 吸电子烯烃, 钯(II)催化

Acetals are very important intermediates in synthetic chemistry. This review presents the recent development in the synthesis of acetals using aldehydes and alkenes as raw materials. The green catalysts and environmentally friendly processes developed for the acetalization reaction were emphatically dis-cussed.

Key words: green chemistry, alkene with electron-withdrawing group, Pd(II)-catalysis, acetalization