有机化学 ›› 2006, Vol. 26 ›› Issue (08): 1039-1051. 上一篇    下一篇

综述与进展

官能团化稠环芳香烃合成进展

程晓红*,1,HOEGER, Sigurd2   

  1. (1云南大学化学与材料工程学院 教育部自然资源化学重点实验室 昆明 650091)
    (2 Institut of Technical Chemistry and Polymerchemisty, Karlsruhe University, Engesserstr. 18, 76131 Karlsruhe, Germany)
  • 收稿日期:2005-07-21 修回日期:2006-01-10 发布日期:2006-07-26
  • 通讯作者: 程晓红

Progress on Synthesis of Functional Polycyclic Aromatic Hydrocarbon

CHENG Xiao-Hong*,1,HOEGER Sigurd2   

  1. (1 Key Laboratory of Medical Chemistry for Natural Resource, Ministry of Education, School of Chemistry and
    Material Engineering, Yunnan University, Kunming 650091, China)
    (2 Institut of Technical Chemistry and Polymerchemisty, Karlsruhe University, Engesserstr. 18, 76131 Karlsruhe, Germany)
  • Received:2005-07-21 Revised:2006-01-10 Published:2006-07-26
  • Contact: CHENG Xiao-Hong

对稠环芳香烃的合成方法、官能团化稠环芳香烃最新合成进展、官能团化稠环芳香烃构建的复杂分子体系(液晶、刚性线型和环状的大分子)及其超分子化学进行了评述.

关键词: 超分子, 稠环芳香烃, 苯基乙炔基, 脱卤化氢, 刚性大环, 液晶

The classic synthesis methods of polycyclic aromatic hydrocarbons (PAH), the most recent development in the synthetic methodology of the functional PAH, their application to construction of complex architectures (liquid crystals, shape persistent linear and cyclic macromolecules), and their supramolecular behavior are reviewed in this article.

Key words: molecular self organization, dehydrohalogenation, phenylene-ethynylene, liquid crystal, shape persistent macromolecules, polycyclic aromatic hydrocarbon