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有机化学
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有机化学 ›› 2000, Vol. 20 ›› Issue (4): 533-536. 上一篇    下一篇

研究论文

1-氨基-2-(2'-甲基-4'-丙酸甲酯)苯氧基-4-羟基蒽醌的合成

胡莹玉;李红斌;孙灵;沈永嘉;邱忠成   

  1. 上海大学环境与建筑工程学院;华东理工大学精细化工研究所;上海分析仪器总 厂
  • 发布日期:2000-08-25

Synthesis of 1-amino-2-(2'-methyl-4'-methyl propionate) phenoxy-4- hydroxy anthraquinone

Hu Yingyu;Li Hongbin;Sun Ling;Shen Yongjia;Qiu Zhongcheng   

  • Published:2000-08-25

PDF

486

被引次数

2

邻甲苯酚与丙烯腈经Friedel-Crafts反应得到了2-甲基-4-β-氰基乙基苯酚，其与1-氨基-2-溴-4-羟基蒽醌经亲核取代形成的产物经水解、酯化得到目标化合物。给出了该化合物及其中间体的质谱、核磁共振氢谱、元素分析、可见光谱及熔点等数据。

关键词: 丙酸酯, 苯氧基, 蒽醌P, 苯酚P, 丙烯腈, 质谱法, 质子磁共振谱法, 元素分析

2-Methyl-4-β-cyanoethylphenol was synthesized via Friedel-Crafts reaction between o-cresol and acrylonitrile. It was condensed with 1- amino-2-bromo-4-hydroxy anthraquinone by the nucleophilic reaction. The product was hydrolyzed in alkaline medium and esterified with methanol to afford the title compound. Mass, ^1H NMR, element analyses, Vis spectra and the melting points of the title compound and the intermediates were measured.

Key words: PROPIONATE, PHENOXY GROUP, ANTHRAQUINONE P, PHENOL P, ACRYLONITRILE, MASS SPECTROGRAPHY, PROTON MAGNETIC RESONANCE SPECTROMETRY, ELEMENTAL ANALYSIS

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