有机化学 ›› 2000, Vol. 20 ›› Issue (6): 841-849.    下一篇

研究论文

桥联杯[6]芳烃研究进展

李建森;陈远荫;卢雪然   

  1. 武汉大学化学系.武汉(430072)
  • 发布日期:2000-12-25

Development in the research of bridged calix[6]arenes

Li Jiansen;Chen Yuanyin;Lu Xueran   

  1. Wuhan Univ, Dept Chem.Wuhan(430072)
  • Published:2000-12-25

综述了桥联杯[6]芳烃的合成及构象固定等方面的研究进展,并以下缘1,4位桥联杯[6]芳烃,杯[6]冠醚和杯[6]穴醚及其类似物等主体分子为重点,综述了桥联杯[6]芳烃在分子识别和超分子化学领域中的应用研究的最新进展。

关键词: 杯芳烃, 构象, 分子识别, 冠醚

Bridged calix[6]arenes, which have the advandge of preorganizing the calixarene conformations suit-able for molecular recognition, are becoming one of the latest central interests in calixarene chemistry. This paper reviews the research progress of bridged calix[6]arenes, including their preparations, conformation immobilization and spectral characteristics, molecular recognition ability, applications in the field of synthetic organic chemistry and supramolecular chemistry. Several types of important members in this family, such as rigid-spacer-briged calix[6]arenes, calix[6]crowns, and calix[6] cryptands are highlighted in detail.

Key words: CALIXARENE, CONFORMATION, OLECULAR RECOGNITION, CROWN ETHER

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