有机化学 ›› 2006, Vol. 26 ›› Issue (01): 87-89. 上一篇    下一篇

研究简报

离子液体中二茂铁甲酸芳香酯的合成研究

陈维一*,陆军,张勇   

  1. (苏州大学化学化工学院 苏州 215006)
  • 收稿日期:2005-03-08 修回日期:2005-07-01 发布日期:2005-12-31
  • 通讯作者: 陈维一

Study of the Synthesis of Aryl Ferrocenecarboxylate in Ionic Liquids

CHEN Wei-Yi*,LU Jun,ZHANG Yong   

  1. (School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006)
  • Received:2005-03-08 Revised:2005-07-01 Published:2005-12-31
  • Contact: CHEN Wei-Yi

在“绿色溶剂”——室温离子液体中, 采用二环己基碳二亚胺/4-二甲氨基吡啶(DCC/DMAP)进行二茂铁甲酸芳香酯的合成研究, 反应条件温和, 简单方便, 产率高, 该反应具有环境友好的特点.

关键词: 二茂铁甲酸, 晶体结构, 离子液体, DCC, 酯化

An efficient esterification of ferrocenecarboxylic acid and substituted phenols has been achieved using DCC/DMAP protocol in ionic liquids. The corresponding esters were produced in high yields.

Key words: ionic liquid, crystal structure, DCC, esterification, ferrocenecarboxylic acid