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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (01): 86-89. 上一篇    下一篇

研究论文

杯[4]芳烃黄原酸酯衍生物的合成与阳离子萃取性能

杨发福*,1,2，陈希磊1，郭红玉1，林深1,2，陈远荫3   

  1. （1福建师范大学化学与材料学院 福州 350007）
    ( 2中国科学院福建物质结构研究所结构化学国家重点实验室 福州 350002)
    (3武汉大学化学系 武汉 430072)
  • 收稿日期:2004-02-27 修回日期:2004-08-25 发布日期:2004-12-30
  • 通讯作者: 杨发福

Syntheses and Complexation Abilities of Calix[4]arene Derivatives Containing Xanthates

YANG Fa-Fu*,1,2,CHEN Xi-Lei1,GUO Hong-Yu1,LIN Shen1,2,CHEN Yuan-Yinc   

  1. (1 Department of Chemistry, Fujian Normal University, Fuzhou 350007)
    (2 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter,
    Chinese Academy of Sciences, Fuzhou 350002)
    (3 Department of Chemistry, Wuhan University, Wuhan 430072)
  • Received:2004-02-27 Revised:2004-08-25 Published:2004-12-30
  • Contact: YANG Fa-Fu

PDF

1597

被引次数

27

以二氧六环作溶剂, 杯[4]芳烃二甲氧基二羟乙氧基衍生物2与氢氧化钾、二硫化碳作用合成了杯芳烃黄原酸盐衍生物3, 并进一步与碘甲烷或氯化苄反应首次合成了含黄原酸酯基的杯芳烃衍生物4a和4b. 阳离子萃取试验表明该新型杯芳烃衍生物比单硫杂杯芳烃衍生物具有更好的过渡金属离子萃取性能.

关键词: 杯[4]芳烃, 黄原酸酯, 络合, 合成

Under the action of CS2 and KOH in dioxane solution, calix[4]arene derivative 2 was converted into calix[4]arene derivative containing xanthate salt 3. Calix[4]arene derivatives containing xanthates 4a and 4b were prepared by the reaction 3 with CH3I or benzyl chloride further. The complexation abilities of novel calixarene derivatives towards transition metal ions were superior to those of monothiocalix[4]arene derivatives.

Key words: complexation, xanthate, synthesis, calix[4]arene