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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (01): 24-33. 上一篇    下一篇

综述与进展

含氟卟啉的研究进展

曾卓*， 廖子英，唐天声，陈超森   

  1. (华南师范大学化学与环境学院有机化学研究所 广州 510006)
  • 收稿日期:2006-01-05 修回日期:2006-03-30 发布日期:2006-12-30
  • 通讯作者: 曾卓

Progress in the Study of Fluoroporphyrins

ZENG Zhuo*,LIAO Zi-Ying,TANG Tian-Sheng,CHEN Chao-Sen   

  1. (Institute of Organic Chemistry, South China Normal University, Guangzhou 510006)
  • Received:2006-01-05 Revised:2006-03-30 Published:2006-12-30
  • Contact: ZENG Zhuo

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被引次数

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综述了近几年国内外含氟卟啉的合成及其研究进展. 含氟卟啉合成方法分为直接氟化法和间接氟化法. 直接法主要采用无机氟化试剂直接对卟啉环进行氟化; 间接法主要采用含氟砌块法引入氟基团. 由于合成卟啉环比较复杂, 目前氟化学家主要采用间接氟化法合成含氟卟啉化合物.

关键词: 间接氟化法, 含氟砌块, 含氟卟啉, 直接氟化法

This review summarizes the recent progress in the research of fluoroporphyrins and its properties. There are two methods for synthesis of the fluoroporphyrins: direct and indirect fluorination. The direct fluorination of porphyrin always involves in using the inorganic fluorination agents to attack the porphyrins while the indirect fluorination of porphyrin employing the fluorinated building block. The fluoroporphyrins are synthesized by the indirect fluorination method more often because the synthesis of porphyrin macrocycle is very complicated.

Key words: indirect fluorination, fluorinated building block, direct fluorination, fluoroporphyrins