SIOC English
有机化学
高级检索

有机化学 ›› 2006, Vol. 26 ›› Issue (11): 1562-1565. 上一篇    下一篇

研究论文

含噻二唑基的对叔丁基杯[4]芳烃衍生物的合成及表征

赵邦屯*,a，王璐b，冶保献*,b   

  1. (a洛阳师范学院化学系 洛阳 471022)
    (b郑州大学化学系 郑州 450001)
  • 收稿日期:2006-02-06 修回日期:1900-01-01 发布日期:2006-10-27
  • 通讯作者: 冶保献

Synthesis and Characterization of p-tert-Butylcalix[4]arene Derivatives Containning Thiadiazole Functional Groups

ZHAO Bang-Tun*,a,WANG Lub,YE Bao-Xian*,b   

  1. (a Department of Chemistry, Luoyang Normal University, Luoyang, 471022)
    (b Department of Chemistry, Zhengzhou University, Zhengzhou, 450001)
  • Received:2006-02-06 Revised:1900-01-01 Published:2006-10-27
  • Contact: YE Bao-Xian

PDF

1110

被引次数

20

以对叔丁基杯[4]芳烃(1)为原料, 分别与1,2-二溴乙烷、1,3-二溴丙烷在碳酸钾的存在下进行选择性烷基化反应, 生成杯[4]芳烃衍生物2和3. 在氢氧化钠存在下, 化合物2和3与过量的含不同官能团的2-巯基噻二唑反应, 生成下缘含噻二唑基的杯芳烃衍生物4a～4c, 5a～5c, 其结构经1H NMR, 13C NMR, IR, MS和元素分析确证.

关键词: 合成, 表征, 杯[4]芳烃衍生物, 噻二唑

The p-tert-butylcalix[4]arene (1) was firstly alkylated with 1,2-dibromoethane and 1,3-dibro- mopropane to give calix[4]arene derivatives 2 and 3 in the presence of potassium carbonate, respectively. A series of p-tert-butylcalix[4]arene derivatives 4a～4c, 5a～5c which append thiadiazolidinyl groups at the lower rims were easily synthesized in good yields by the reaction of compounds 2 or 3 with 2-mercapto- thiadiazole. All new compounds were characterized by 1H NMR, 13C NMR, IR, MS spectra and elemental analysis.

Key words: synthesis, characterization, thiadiazole, calix[4]arene derivative