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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (08): 1011-1014. 上一篇    

研究简报

氧化铝催化下环氧烷与芳胺的反应——β-氨基醇的合成

谭伟，赵宝祥*，沙磊，焦培福，万茂生，苏磊   

  1. (1山东大学化学与化工学院有机化学研究所 济南 250100)
    (2山东省农药研究所 济南 250100)
  • 收稿日期:2004-11-16 修回日期:2005-03-02 发布日期:2005-07-30
  • 通讯作者: 赵宝祥

Alumina Catalyzed Synthesis of β-Aminoalcohols from Epoxides and Aromatic Amines

TAN Wei,ZHAO Bao-Xiang*,SHA Lei
JIAO Pei-Fu,WAN Mao-Sheng,SU Lei   

  1. (1 Institute of Organic Chemistry, School of Chemical Engineering, Shandong University, Jinan 250100)
    (2 Institute of Pesticide of Shangdong Province, Jinan 250100)
  • Received:2004-11-16 Revised:2005-03-02 Published:2005-07-30
  • Contact: ZHAO Bao-Xiang

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在氧化铝催化下, 以芳氧甲基环氧烷和芳胺为原料, 合成了一系列1-芳氧基-3-芳氨基异丙醇衍生物. 产物结构均由IR, MS和1H NMR进行表征.

关键词: 环氧烷, 芳胺, 氧化铝, 1-芳氧基-3-芳氨基异丙醇

A series of 1-aroxy-3-arylamino-2-propanol derivatives have been synthesized by the reaction of 2-(aroxymethyl)oxiranes with aromatic amines in the presence of alumina. The structures of products were confirmed by IR, MS and 1H NMR spectra.

Key words: alumina, 1-aroxy-3-arylamino-2-propanol, aromatic amine, epoxide