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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (11): 1319-1333.    下一篇

综述与进展

手性二胺的合成及其在催化不对称反应中的应用

艾林，肖季川，申秀民，张聪*   

  1. (北京师范大学化学系 北京 100875)
  • 收稿日期:2004-08-31 修回日期:2005-03-24 发布日期:2005-10-30
  • 通讯作者: 张聪

Synthesis of Chiral Diamines with C2 Symmetry and Their Applications to Catalytic Asymmetric Reactions

AI Lin, XIAO Ji-Chuan, SHEN Xiu-Min, ZHANG Cong*   

  1. (Department of Chemistry, Beijing Normal University, Beijing 100875)
  • Received:2004-08-31 Revised:2005-03-24 Published:2005-10-30
  • Contact: ZHANG Cong

PDF

4936

被引次数

9

手性二胺作为具有良好催化活性和对映选择性的手性配体或手性辅助剂, 在多种催化不对称反应中已经得到广泛应用, 并取到了很好的研究成果. 目前, 手性二胺化学的研究已成为催化不对称化学领域中一个十分活跃和引人注目的研究热点. 综述了手性二胺化学近几年的研究进展.

关键词: 手性二胺, 合成, 应用, 催化不对称反应

Chiral diamines have been employed in catalytic asymmetric reactions as chiral ligands or auxiliaries with excellent catalytic activity and enantioselectivity. At present, studies on and applications of chiral diamines have been regarded as one of the most remarkable fields in catalytic asymmetric reactions. This review described the development of chiral diamines in recent years.

Key words: synthesis, chiral diamine, catalytic asymmetric reaction, application