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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (05): 745-748. 上一篇    下一篇

研究简报

含均三嗪环氮杂环蕃合成与表征

吕国华, 花成文, 苟小锋, 刘艳凤   

  1. (西北大学化学与材料科学学院 合成与天然功能分子化学教育部重点实验室 西安 710069)
  • 收稿日期:2009-09-08 修回日期:2009-11-25 发布日期:2009-12-17
  • 通讯作者: 花成文 E-mail:huachengwen@126.com

Synthesis and Characterization of Azacyclophanes Containing 1,3,5-Triazine

Lü Guo-Hua , HUA Cheng-Wen, GOU Xiao-Feng, LIU Yan-Feng   

  1. (Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi an 710069)
  • Received:2009-09-08 Revised:2009-11-25 Published:2009-12-17

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1599

被引次数

26 | 6

环蕃具有空腔结构, 从而显示出许多独特的性质, 有很大的应用前景. 为了做进一步的研究, 用三聚氯氰、苯酚, 甲醇钠、1,6-己二胺、4,4 -二氨基-二苯甲烷为原料, 经多步取代合成了几种新的氮杂环蕃, 并用1H NMR, IR , MALDI-TOF-MS和元素分析对其结构进行了表征. 同时对实验中所用的溶剂、缚酸剂以及反应浓度都进行了实验探索, 得到了反应的最佳条件.

关键词: 三聚氯氰, 环蕃, 合成, 表征

Cyclophane with a cavity structure, has a great potential prospects. Some novel azacyclophanes were synthesized from cyanuric chloride, phenol, sodium methoxide, 1,6-hexane diamine and 4,4 -diaminodiphenyl methane by substitution, and their structures were characterized by 1H NMR, IR, MALDI-TOF-MS techniques and elemental analysis. A large number of experiments have been carried out to explore the solvent, alkal and concentration to find out the best reaction conditions.

Key words: cyanuric chloride, cyclophane, synthesis, characterization