有机化学 ›› 2010, Vol. 30 ›› Issue (05): 757-759. 上一篇    下一篇

研究简报

邻芳基苯基膦酸酯的新合成路线

王勇,吴梅,丁贻祥*   

  1. (中国科学院上海有机化学研究所 上海 200032)
  • 收稿日期:2009-08-06 修回日期:2009-11-03 发布日期:2009-12-28
  • 通讯作者: 丁贻祥 E-mail:dingyx@mail.sioc.ac.cn
  • 基金资助:

    国家级.国家自然科学基金

A New Route for Synthesis of o-Arylphenylphosphonates

WANG Yong, WU Mei, DING Yi-Xiang   

  1. (Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032)
  • Received:2009-08-06 Revised:2009-11-03 Published:2009-12-28

以磷酸苯酯为原料, 经碱性重排、O-磺酰化和Suzuki偶联反应合成邻芳基苯基膦酸酯是一条方便合理的路线.

关键词: 膦酸苯酯重排, 邻芳基苯基膦酸酯, Suzuki偶联

A convenient and applicable route has been developed to synthesize various o-arylphenylphos- phonates starting from phenyl phosphates via Melvin rearrangement, O-sulfonylation and Suzuki coupling.

Key words: o-arylphenylphosphonate, rearrangement of phenyl phosphate, Suzuki coupling