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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (01): 141-147. 上一篇    下一篇

学术动态

硼杂环戊二烯化合物研究进展

聂永*，陈洪伟，苗金玲，陈海艳，孙国新   

  1. (济南大学化学化工学院 山东省氟化学化工材料重点实验室 济南 250022)
  • 收稿日期:2010-03-28 修回日期:2010-05-31 发布日期:2010-08-04
  • 通讯作者: 聂永 E-mail:chm_niey@ujn.edu.cn
  • 基金资助:

    国家自然科学基金;教育部留学回国人员基金

Advances in the Chemistry of Boroles

NIE Yong, CHEN Hong-Wei, MIAO Jin-Ling, CHEN Hai-Yan, SUN Guo-Xin   

  1. (Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022)
  • Received:2010-03-28 Revised:2010-05-31 Published:2010-08-04

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被引次数

4

硼杂环戊二烯(H4C4BH)衍生物具有4π电子反芳香性结构和很强的Lewis酸性, 在理论和应用(光电功能材料和烯烃聚合催化剂等)上都有重要研究价值. 综述了近三年来硼杂环戊二烯化合物的研究进展, 着重讨论了其合成、结构和化学反应性, 归纳了硼杂环戊二烯(基)配合物的合成方法与结构类型.

关键词: 硼杂环戊二烯, 反芳香性, 合成, 反应性, 夹心化合物

With the 4π electron anti-aromatic structure and high Lewis acidity, borole (H4C4BH) derivatives have received much interest in both theory and potential applications (optoelectronic materials, ethylene polymerization catalysis, etc.). In this review, the most recent advances of the synthesis, structure and reactivity of borole derivatives, as well as the synthetic methods and structural types of borol(yl) metal complexes are summarized.

Key words: borole, anti-aromaticity, synthesis, reactivity, sandwich complex