有机化学 ›› 2011, Vol. 31 ›› Issue (12): 2034-2042. 上一篇    下一篇

综述与进展

贝克曼重排反应研究进展

李倩,严罗一,夏定,申永存*   

  1. (武汉理工大学化工学院 武汉 430070)
  • 收稿日期:2010-10-02 修回日期:2011-01-04 发布日期:2011-06-17
  • 通讯作者: 申永存 E-mail:yongcunshen@163.com

Research Progress of Beckmann rearrangement

LI Qian, YAN Luo-Yi, XIA Ding, SHEN Yong-Cun   

  1. (Institute of Chemical Engineering, Wuhan University of Technology, Wuhan 430070)
  • Received:2010-10-02 Revised:2011-01-04 Published:2011-06-17
  • Contact: CUN YONGSHEN E-mail:yongcunshen@163.com

贝克曼(Beckmann)重排反应早在19世纪就被发现, 是由肟制备酰胺的常用方法之一, 但至今研究仍不够深入, 亟待发展和研究. 对贝克曼重排反应的发展及研究状况作了综述.

关键词: 贝克曼(Beckmann)重排, 酮肟, 酰胺, 综述

Beckmann rearrangement has been found early in nineteenth century, which was commonly used in organic chemistry to transform ketoximes into amides. It is a topic of current interest but not in-depth, which is in need of further development and research. In this paper, the progress of Beckmann rearrangement reactions in recent years is reviewed.

Key words: Beckmann rearrangement, ketoxime, amide, review