异伍兹烷衍生物的研究进展

doi:10.6023/cjoc1104225

摘要/Abstract

六硝基六氮杂异伍兹烷(HNIW 或CL-20)是当今世界上综合性能最好的单质炸药, 在20 余年的研究过程中, 各国研究者合成出了百余种异伍兹烷衍生物. 根据笼体上取代基的不同以及合成反应的类型, 系统总结了各类衍生物的合成、用途及反应性. 最后对异伍兹烷衍生物的发展方向进行了展望.

关键词: 异伍兹烷衍生物, 高能量密度化合物, 综述

Hexanitrohexaazaisowurtzitane (HNIW or CL-20) is presently the most powerful energetic compound in the world. The synthesis of CL-20 or cage molecules has attracted considerable interest of experts in the area of high-energy materials over the last two decades, and more than 100 isowurtzitane derivatives were synthesized. In this paper, the synthesis, application and reactivity of these compounds are summarized systematically according to different substituents on the cage and types of reactions. The developing tends of isowurtzitane derivatives are also presented.

Key words: isowurtzitane derivatives, high energy density compound, review

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公绪滨, 孙成辉, 庞思平, 张静, 李玉川, 赵信岐. 异伍兹烷衍生物的研究进展[J]. 有机化学, 2012, (03): 486-496.

Gong Xubin, Sun Chenghui, Pang Siping, Zhang Jing, Li Yuchuan, Zhao Xinqi . Research Progress in Study of Isowurtzitane Derivatives[J]. Chin. J. Org. Chem., 2012, (03): 486-496.

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