乙烯基碳上的亲核取代反应

doi:10.6023/cjoc201406046

摘要/Abstract

综述了近二十年来关于sp²杂化碳, 主要是乙烯基碳上发生的亲核取代反应的研究进展. 讨论了乙烯基碳上的亲核取代反应的理论支持, 阐明了其在有机合成中, 特别是在杂环化合物的合成中的重要应用. 同时还总结了其他不饱和原子如sp²杂化氮的亲核取代反应的研究以及应用.

关键词: 乙烯基碳, sp²杂化碳, 亲核取代反应, sp²杂化氮

The recently research progress in the nucleophilic substitution reactions at the sp²-carbons, mainly at the vinylic carbons is reviewed. The theoretical studies on the nucleophilic substitution reactions at the vinylic carbons, and their applications in organic synthesis, especially in the synthesis of heterocycle compounds, are illustrated. And, researches and applications of the nucleophilic substitution reactions at other unsaturated atoms like sp² nitrogens are also discussed.

Key words: inylic carbon, sp² carbon, nucleophilic substitution reaction, sp² nitrogen

引用此文

沈舒苏. 乙烯基碳上的亲核取代反应[J]. 有机化学, 2014, 34(12): 2448-2455.

Shen Shusu. Nucleophilic Substitution Reactions at Vinylic Carbons[J]. Chin. J. Org. Chem., 2014, 34(12): 2448-2455.

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