有机化学 ›› 2015, Vol. 35 ›› Issue (6): 1229-1237.DOI: 10.6023/cjoc201412018 上一篇    下一篇

综述与进展

卟啉敏化太阳能电池研究进展

顾承志a,b, 孟舒献a, 冯亚青a,c   

  1. a 天津大学化工学院 天津 300072;
    b 石河子大学化学化工学院 石河子 832000;
    c 天津化学与化工协同创新中心 天津 300072
  • 收稿日期:2014-12-11 修回日期:2015-01-05 发布日期:2015-02-02
  • 通讯作者: 冯亚青 E-mail:yqfeng@tju.edu.cn
  • 基金资助:

    国家自然科学基金(Nos. 21076147, 21476162)、国家国际科技合作专项(No. 2012DFG41980)资助项目.

Progress of Porphyrin Sensitizers for Dye-Sensitized Solar Cells

Gu Chengzhia,b, Meng Shuxiana, Feng Yaqinga,c   

  1. a School of Chemical Engineering, Tianjin University, Tianjin 300072;
    b School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000;
    c Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072
  • Received:2014-12-11 Revised:2015-01-05 Published:2015-02-02
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21076147, 21476162) and the National International S&T Cooperation Foundation of China (No. 2012DFG41980).

由于自然界中光合作用的核心结构是卟啉, 其具有良好的光、热和化学稳定性, 在过去的二十年中卟啉染料敏化太阳能电池研究获得了极大的关注, 2014年卟啉染料光电转换效率突破了13%, 成为新的基准效率. 以光电性能为主线, 从分子工程设计的角度出发, 系统性地总结了应用于敏化太阳能电池的不同结构卟啉染料性能的研究进展.

关键词: 染料敏化太阳能电池, 卟啉, 分子工程设计, 光电性能

As a core structure of nature photosynthesis, porphyrin has good light, thermal and chemical stability. In the past two decades, porphyin based dye-sensitized solar cells (DSSC) has attracted much attention relevant to global environmental issues. Up to date, they exhibit the best performance with a benchmark efficiency of 13% reported in 2014 for dye-sensitised solar cells. The progress of porphyrins and their derivatives applied in DSSC from the point of view of molecular engineering design correlated with photovoltaic performance is systematically summarized.

Key words: dye-sensitized solar cells, porphyin, molecular engineering design, photovoltaic performance