水相中由壳聚糖-铜催化合成苯酚的方法研究

doi:10.6023/cjoc201510027

有机化学 ›› 2016, Vol. 36 ›› Issue (4): 862-866.DOI: 10.6023/cjoc201510027 上一篇下一篇

研究简报

水相中由壳聚糖-铜催化合成苯酚的方法研究

赵苏艳^a, 王祖利^b

a. 吉林警察学院实验技术中心长春 130117;
b. 青岛农业大学化学与药学院青岛 266109

收稿日期:2015-10-23 修回日期:2015-11-16 发布日期:2015-12-10
通讯作者: 王祖利 E-mail:wangzulichem@163.com
基金资助:
国家自然科学基金(No.21402103)、山东省优秀中青年基金(No.BS2013YY024)、中国博士后基金(No.150030)资助项目.

Synthesis of Phenols under Mild Conditions in Water Using Recyclable Chitosan@Copper as Catalyst

Zhao Suyan^a, Wang Zuli^b

a. Jilin Police College Experimental Technology Center, Changchun 130117;
b. College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109

Received:2015-10-23 Revised:2015-11-16 Published:2015-12-10
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21402103), the Scientific Research Foundation of Shandong Province Outstanding Young Scientist Award (No. BS2013YY024), and the Postdoctoral Science Foundationof China (No. 150030).

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1. 水相中由壳聚糖-铜催化合成苯酚的方法研究.PDF(1943KB)

摘要/Abstract

壳聚糖负载的铜催化剂催化下,以苯硼酸为原料,在碱的水溶液中反应合成苯酚.此方法反应条件温和,操作简单,生成的苯酚产率高,反应以水为溶剂,对环境友好.催化剂容易回收,可以重复使用5次且催化剂的活性没有明显降低.

关键词: 壳聚糖负载铜催化剂, 可回收利用, 苯硼酸, 水溶剂

A green and efficient protocol for the synthesis of phenols using recyclable chitosan@copper as catalyst was developed. Phenols can be obtained in moderate to excellent yields. The catalyst can be recycled and reused for five times without significant loss of its catalytic activity.

Key words: chitosan@copper, recyclable, phenylboronic acid, water

引用此文

赵苏艳, 王祖利. 水相中由壳聚糖-铜催化合成苯酚的方法研究[J]. 有机化学, 2016, 36(4): 862-866.

Zhao Suyan, Wang Zuli. Synthesis of Phenols under Mild Conditions in Water Using Recyclable Chitosan@Copper as Catalyst[J]. Chin. J. Org. Chem., 2016, 36(4): 862-866.

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水相中由壳聚糖-铜催化合成苯酚的方法研究

Synthesis of Phenols under Mild Conditions in Water Using Recyclable Chitosan@Copper as Catalyst

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