CO2均相催化氢化研究进展

doi:10.6023/cjoc201702038

摘要/Abstract

由于近年来可持续发展战略的兴起和对全球变暖问题关注，二氧化碳（CO₂）作为资源用于化学合成已经引起越来越多化学家的兴趣.而在利用CO₂的研究中，催化氢化CO₂是CO₂资源利用的重要手段之一，均相催化反应具有反应条件温和、活性高及催化体系易于调控等优点，使得CO₂均相催化氢化尤其是催化生产甲酸、甲醛、甲醇以及胺类化合物衍生物等方面成为当前CO₂资源合理利用的重要课题，具有广阔的应用前景.对近年来金属有机络合物催化的均相氢化CO₂的研究进展进行了综述，主要介绍了催化生产甲酸、甲醛、甲醇以及作为C₁合成子方面中的均相催化剂的种类与结构、活性与选择性以及均相催化氢化CO₂的反应机理等方面的研究.

关键词: 均相催化氢化, CO₂, 金属有机络合物

In recent years, due to the rising of sustainable development strategies and concerns about global warming, chemists have pay more attention to the application of carbon dioxide (CO₂) as a resource for chemical synthesis. Thereinto, in the research of the using of CO₂, catalytic hydrogenation of CO₂ is one of the momentous means for the utilization of CO₂. The homogeneous catalytic reaction has the advantage of mild reaction condition, high activity and easy regulation of the catalytic system and so forth, so the homogeneous catalytic hydrogenation CO₂ becomes to be a hot topic in utilization of CO₂ resource, especially in the catalytic production of formic acid, formaldehyde, methanol and amine derivatives, it has extensive application prospects. In this paper, the recent progress in the research of homogeneously hydrogenated CO₂ catalyzed by organometallic complexes is reviewed. It included that types and structures, activity and selectivity of homogeneous catalysts for the catalytic production of formic acid, formaldehyde, mathanol and as C₁ synthons, and the advance in the reaction mechanism of homogeneous catalytic hydrogenation of CO₂.

Key words: homogeneous catalytic hydrogenation, carbon dioxide, organometallic complexes

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李勇, 王征, 刘庆彬. CO₂均相催化氢化研究进展[J]. 有机化学, 2017, 37(8): 1978-1990.

Li Yong, Wang Zheng, Liu Qingbin. Progress in Homogeneous Catalytic Hydrogenation of CO₂[J]. Chin. J. Org. Chem., 2017, 37(8): 1978-1990.

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CO₂均相催化氢化研究进展

Progress in Homogeneous Catalytic Hydrogenation of CO₂

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