有机化学 ›› 2016, Vol. 36 ›› Issue (12): 2813-2821.DOI: 10.6023/cjoc201606007 上一篇    下一篇

综述与进展

过渡金属催化CO2与C-H键直接羧化反应的研究进展 2017-2018 Awarded

朱庆a,b, 王露a, 夏春谷a, 刘超a   

  1. a 中国科学院兰州化学物理研究所 兰州 730000;
    b 中国科学院大学 北京 100049
  • 收稿日期:2016-06-02 修回日期:2016-08-02 发布日期:2016-08-25
  • 通讯作者: 刘超 E-mail:chaoliu@licp.cas.cn

Recent Advance of Transition Metal-Catalyzed Direct C-H Bond Carboxylation with CO2

Zhu Qinga,b, Wang Lua, Xia Chungua, Liu Chaoa   

  1. a Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
    b University of Chinese Academy of Science, Beijing 100049
  • Received:2016-06-02 Revised:2016-08-02 Published:2016-08-25

CO2是目前最大的碳源之一,将CO2用于合成有机化合物无疑是清洁能源利用的一种新策略,作为CO2参与有机合成反应的主要产物,羧酸及其衍生物也有着广泛的应用.在众多CO2参与的羧化反应方法中,C-H键与CO2的直接羧化反应是最高效的同时也是目前研究十分热门的一类有机化学反应.对近年来CO2与不同杂化态C-H键的直接羧化反应的研究进行总结,主要讲述过渡金属催化的反应体系.

关键词: C-H羧化, CO2, 过渡金属催化

Carbon dioxide represents the most abundant carbon source in the world. It is obvious that the utilization of CO2 to generate chemical products will provide a new strategy for clean energy. Meanwhile, as the main product of CO2 reactions, carboxylic acids and derivatives have wide application. Among various CO2 involved carboxylation reactions, the direct carboxylation of C-H bond with CO2 has attracted much attention recently, which lies in its high efficiency for the synthesis of carboxylic acids. This review summarizes the direct carboxylation of different hybrid C-H bonds with CO2 in recent years, which focus on transition metal catalyzed reactions for the synthesis of carboxylic acids and its derivatives from CO2.

Key words: C-H carboxylation, CO2, Transition metal catalysis