有机化学 ›› 2017, Vol. 37 ›› Issue (10): 2569-2589.DOI: 10.6023/cjoc201702033 上一篇    下一篇

综述与进展

碳亲核试剂对氮杂环丙烷的开环反应研究进展

褚旭, 常宏宏, 高文超, 魏文珑, 李兴   

  1. 太原理工大学化学化工学院 生物与制药工程系 太原 030024
  • 收稿日期:2017-02-23 修回日期:2017-05-03 发布日期:2017-06-02
  • 通讯作者: 李兴 E-mail:lixing@tyut.edu.cn
  • 基金资助:

    山西省自然科学基金(Nos.201601D011028,20130110094)资助项目.

Research Progress in the Ring-Opening Reactions of Aziridines by Carbon Nucleophiles

Chu Xu, Chang Honghong, Gao Wenchao, Wei Wenlong, Li Xing   

  1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024
  • Received:2017-02-23 Revised:2017-05-03 Published:2017-06-02
  • Contact: 10.6023/cjoc201702033 E-mail:lixing@tyut.edu.cn
  • Supported by:

    Project supported by the Natural Science Foundation of Shanxi Province (Nos.201601D011028,20130110094).

综述了各种碳亲核试剂对氮杂环丙烷的开环反应研究进展,主要包括炔、腈、芳烃、芳香杂环化合物、活泼亚甲基和有机金属试剂等作为碳亲核试剂发生的开环反应,并对其发展方向进行了展望.

关键词: 氮杂环丙烷, 开环反应, 碳亲核试剂

The recent progress in ring-opening reactions of aziridines by various carbon nucleophiles, such as alkynes, nitriles, arenes, heteroarenes, active methylene compounds, organometallic reagents and so on, is reviewed. Moreover, the prospects of future development are also discussed.

Key words: aziridines, ring-opening reactions, carbon nucleophiles