有机化学 ›› 2018, Vol. 38 ›› Issue (10): 2519-2533.DOI: 10.6023/cjoc201804017 上一篇    下一篇

综述与进展

无过渡金属参与的羰基化反应进展

徐方宁, 韩维   

  1. 南京师范大学化学与材料科学学院 南京 210023
  • 收稿日期:2018-04-10 修回日期:2018-05-28 发布日期:2018-06-07
  • 通讯作者: 韩维,E-mail:hanwei@njnu.edu.cn E-mail:hanwei@njnu.edu.cn
  • 基金资助:

    国家自然科学基金(No.21776139)、江苏省自然科学基金(No.BK20161553)、江苏省高校自然科学基金(No.16KJB150019)、南京师范大学青蓝工程和江苏省优势学科资助项目.

Research Progress in Transition-Metal-Free Carbonylation Reactions

Xu Fangning, Han Wei   

  1. School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023
  • Received:2018-04-10 Revised:2018-05-28 Published:2018-06-07
  • Contact: 10.6023/cjoc201804017 E-mail:hanwei@njnu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21776139), the Natural Science Foundation of Jiangsu Province (No. BK20161553), the Natural Science Foundation of Jiangsu Provincial Colleges and Universities (No. 16KJB150019), the Qing Lan Project of Nanjing Normal University and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

一氧化碳是来源广泛和廉价的碳一资源.直接将其作为羰基源引入有机分子中的羰基化反应是化学化工研究的前沿领域之一.近年来,无过渡金属参与的羰基化反应引起了人们的高度关注.综述了无过渡金属参与的羰基化合成醛与酮、合成酯、合成酰胺、合成酸和酸酐以及合成酰氯和醇等重要羰基化反应的研究现状,并对无过渡金属参与的羰基化反应的发展及应用前景进行了展望.

关键词: 一氧化碳, 羰基化, 无过渡金属, 合成方法

Carbon monoxide is a readily available and cheap C1 feedstock. Carbonylation, the direct incorporation of carbon monoxide into organic molecules, is a very important and fundamental chemical transformation. In recent years, developing transition-metal-free systems for the carbonylation has attracted highly attention from many researchers. The recent rearch progress of transition-metal-free carbonylations for the synthesis of aldehydes, ketones, esters, amides, acids, anhydrides, acyl chloride, and alcohols is reviewed. And the development and application prospects for transition-metal-free carbonylation are also discussed.

Key words: carbon monoxide, carbonylation, transition-metal-free, synthetic methods