有机化学 ›› 2004, Vol. 24 ›› Issue (5): 547-549. 上一篇    下一篇

研究简报

两种新型salen金属络合物WO2(salen)和MoO2(salen)的合成

孙川, 王歆燕, 张治国, 石鸿昌*   

  1. 清华大学化学系 北京 100084
  • 收稿日期:2003-07-15 修回日期:2003-09-29 接受日期:2003-11-12 发布日期:2022-09-20

Synthesis of WO2(salen) and MoO2(salen) Complexes

SUN, Chuan, WANG, Xin-Yan, ZHANG, Zhi-Guo, SHI, Hong-Chang*   

  1. Department of Chemistry, Tsinghua University, Beijing 100084
  • Received:2003-07-15 Revised:2003-09-29 Accepted:2003-11-12 Published:2022-09-20
  • Contact: *E-mail: shihc@mail.tsinghua.edu.cn; Tel: 01062783878.

新合成了两种过渡金属salen络合物WO2(salen)和MoO2(salen).通过和已经有的文献比较,发现这两种络合物的分子结构是少见的β-cis构型.

关键词: 合成, salen, WO2(salen), MoO2(salen)

The transition metal salen complexes, WO2(salen) and MoO2(salen), were synthesized. Compared with known complexes, WO2(salen)and MoO2(salen) adopt seldom β-cis configuration.

Key words: synthesis, salen, WO2(salen), MoO2(salen)