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有机化学
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有机化学 ›› 2004, Vol. 24 ›› Issue (8): 950-952. 上一篇    下一篇

研究简报

对苯二甲醛或间苯二甲醛与5,5-二甲基-1,3-环己二酮的反应:含有双4(H)-吡喃、1,4-二氢吡啶结构单元的杂环化合物的合成

冯友健, 章晓镜, 缪春宝, 蒋虹, 屠树江*   

  1. 徐州师范大学化学系 江苏省药用植物生物技术重点实验室 徐州 221009
  • 收稿日期:2003-10-21 修回日期:2004-02-28 接受日期:2004-02-28 发布日期:2022-09-20
  • 通讯作者: * E-mail: laotu2001@263.net
  • 基金资助:
    国家自然科学基金 (No. 20372057)、江苏省自然科学基金 (No. BK2001142)、江苏省教育厅自然科学基金(No. 01KJB150008)资助项目.

Reaction of Aromatic Dialdehyde with 5,5-Dimethyl-1,3-cyclohexanedione: Synthesis of Heterocyclic Compounds Containing Two 4H-Pyran or Two 1,4-Dihydropyridine Building Blocks

FENG You-Jian, ZHANG Xiao-Jing, MIAO Chun-Bao, JIANG Hong, TU Shu-Jiang*   

  1. Department of Chemistry, Xuzhou Normal University, Key Laboratory of Biotechnology on Medical Plant, Xuzhou 221009
  • Received:2003-10-21 Revised:2004-02-28 Accepted:2004-02-28 Published:2022-09-20

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用对苯二甲醛或间苯二甲醛与5,5-二甲基-1,3-环己二酮反应,在不同条件下得到了含有双4(H)-吡喃、1,4-二氢吡啶结构单元的双-氧杂蒽衍生物、双-吖啶衍生物、以及双-N-羟基吖啶衍生物.

关键词: 对苯二甲醛, 间苯二甲醛, 5,5-二甲基-1,3-环己二酮, 吖啶, 氧杂蒽

The bis-oxanthene, bis-polyhydroacridine and bis-N-hydroxylacridine derivatives containing bis-4H-pyran or bis-1,4-dihydropyridine (DHP) units were obtained by the reaction of aromatic dialdehydes with 5,5-dimethyl-1,3-cyclohexanedione under different conditions.

Key words: aromatic dialdehyde, 5,5-dimethyl-1,3-cyclohexanedione, acridine, N-hydroxylacridine