关于惰性含氟温室气体转化与利用的研究进展

doi:10.6023/cjoc202401004

有机化学 ›› 2024, Vol. 44 ›› Issue (6): 1831-1852.DOI: 10.6023/cjoc202401004 上一篇下一篇

综述与进展

关于惰性含氟温室气体转化与利用的研究进展

邹震雷^a^,^b,†, 李和寅^b,†, 黄梦君^b, 沈胤朴^b, 刘继阳^b, 王之兆^b, 张为钢^b^,^*(), 王毅^b^,^*(), 潘毅^b

a 铜陵学院电气工程学院光电子应用安徽省工程技术研究中心仿生能源实验室安徽铜陵 244000
b 南京大学化学化工学院配位化学国家重点实验室江苏省先进有机材料重点实验室南京 210033

收稿日期:2024-01-05 修回日期:2024-02-02 发布日期:2024-02-27
作者简介:
^†共同第一作者
基金资助:
国家自然科学基金(21971107); 国家自然科学基金(22071101); 国家自然科学基金(22271147); 铜陵学院基金(2023tlxyrc15)

Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases

Zhenlei Zou^a^,^b,†, Heyin Li^b,†, Mengjun Huang^b, Yinpu Shen^b, Jiyang Liu^b, Zhizhao Wang^b, Weigang Zhang^b,*(), Yi Wang^b,*(), Yi Pan^b,*

a AnHui Technology Research Center of Optoelectronic Technology Appliance, Biomimetic Energy Laboratory, School of Electrical Engineering, Tongling University, Tongling, Anhui 244000
b State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210033

Received:2024-01-05 Revised:2024-02-02 Published:2024-02-27
Contact: * E-mail: zwgqlsfxy@163.com;yiwang@nju.edu.cn
About author:
^†These authors contributed equally to this work.
Supported by:
National Natural Science Foundation of China(21971107); National Natural Science Foundation of China(22071101); National Natural Science Foundation of China(22271147); Foundation of Tongling University(2023tlxyrc15)

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摘要/Abstract

过去的几十年里, 含氟气体因其特殊理化性质, 在人类社会中的应用几乎随处可见, 为人们的生产生活提供了诸多便利的同时, 正悄无声息地引起一系列环境危机. 长期研究表明含氟气体所造成的温室效应远高于其他温室气体, 人们不得不对含氟气体的使用进行重新评估. 为有效实现含氟气体的经济效益最大化及降低环境污染, 科学家们正努力开发含氟温室气体转化利用的新方法. 综述了近20年国内外化学家针对氟利昂、硫酰氟、三氟化氮和六氟化硫等惰性含氟温室气体转化与利用的最新研究成果.

关键词: 惰性含氟温室气体, 氟利昂, 硫酰氟, 三氟化氮, 六氟化硫

Over the past few decades, fluorinated greenhouse gases have been used almost everywhere in human society due to their special physical and chemical properties. In spite of the convenience they provide to peopleʼs production and life, they also cause many environmental problems. The relevant studies have shown that the release of fluorinated gases causes a more serious greenhouse effect than normal greenhouse gases. Therefore, the use of fluorinated gases must be reassessed. In order to maximize the economic benefits of fluorinated gases and reduce their environmental pollution, scientists all over the world are trying to develop new methods for the conversion and utilization of fluorinated greenhouse gases. we aim to provide an overview of the conversion and utilization of fluorinated greenhouse gases, such as freon, sulfuryl fluoride, nitrogen trifluoride and sulfur hexafluoride from 2000 to 2023.

Key words: inert fluorinated greenhouse gas, freon, sulfuryl fluoride, nitrogen trifluoride, sulfur hexafluoride

引用此文

邹震雷, 李和寅, 黄梦君, 沈胤朴, 刘继阳, 王之兆, 张为钢, 王毅, 潘毅. 关于惰性含氟温室气体转化与利用的研究进展[J]. 有机化学, 2024, 44(6): 1831-1852.

Zhenlei Zou, Heyin Li, Mengjun Huang, Yinpu Shen, Jiyang Liu, Zhizhao Wang, Weigang Zhang, Yi Wang, Yi Pan. Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases[J]. Chinese Journal of Organic Chemistry, 2024, 44(6): 1831-1852.

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图/表 39

图式1. 惰性含氟温室气体的转化与利用

Scheme 1. Conversion and use of inert fluorinated greenhouse gases

图式2. 氟利昂-22的卡宾活化模式

Scheme 2. Carbine activation model for Freon-22

图式3. 基于氟利昂-22连续流合成偕二氟烯烃及氘代二氟甲基醇

Scheme 3. Continuous flow synthesis of ketodifluoroolefins and deuterodifluoromethyl alcohols based on Freon-22

图式4. 光催化三甲胺基硼烷活化氟利昂-22的策略

Scheme 4. Strategies for photocatalytic trimethylaminoborane activation of Freon-22

图式5. 光催化三甲胺基硼烷活化氟利昂-22策略的可能机理

Scheme 5. Possible mechanisms of the photocatalytic trimethylaminoborane activation strategy for Freon-22

图式6. 相转移催化剂四苯基氯化砷活化氟利昂-22的策略

Scheme 6. Strategy for the activation of Freon-22 by the phase transfer catalyst tetraphenylarsenic chloride

图式7. 苯硼酸与ClCF2H参与的钯催化偶联反应

Scheme 7. Palladium-catalyzed coupling reactions involving phenylboronic acid and ClCF2H

图式8. 芳基溴化物与ClCF2H参与的钯催化偶联反应

Scheme 8. Palladium-catalyzed coupling reactions involving aryl bromides and ClCF2H

图式9. 苯乙炔与ClCF2H参与的钯催化偶联反应

Scheme 9. Palladium-catalyzed coupling reactions involving phenylacetylene and ClCF2H

图式10. 芳基氯化物与ClCF2H参与的镍催化还原偶联反应

Scheme 10. Nickel-catalyzed reduction coupling reactions involving aryl chlorides and ClCF2H

图式11. 氨基酸衍生物的铜催化不对称二氟甲基化反应

Scheme 11. Copper-catalysed asymmetric difluoromethylation of amino acid derivatives

图式12. 氟仿的传统活化模式及重要的亲核三氟甲基试剂

Scheme 12. Traditional activation modes of fluoroform and important nucleophilic trifluoromethyl reagents

图式13. 氟仿的传统活化模式及重要的亲核三氟甲基试剂

Scheme 13. Copper-catalyzed asymmetric difluoromethylation of amino acid derivatives

图式14. 氟磺酸酯、氟磺酰胺的合成

Scheme 14. Synthesis of fluorosulfonates and fluorosulfonamides

图式15. 氟磺酸酯的衍生化

Scheme 15. Derivatisation of fluorosulfonates

图式16. 芳基氟磺酸酯参与的亲核取代反应与金属偶联反应

Scheme 16. Nucleophilic substitution and metal coupling reactions involving aryl fluorosulfonates

图式17. C—SO2F键的构建

Scheme 17. Construction of the C—SO2F bond

图式18. 新型磺酰氟咪唑盐试剂用于N—SO2F、O—SO2F键的构建

Scheme 18. Novel sulfonylfluorimidazole salt reagents for the construction of N—SO2F, O—SO2F bonds

图式19. 基于氟氯磺酰光催化合成烯基磺酰氟化合物策略

Scheme 19. Photocatalytic synthesis of alkenylsulfonyl fluoride based on fluorochlorosulfonyls

图式20. 氟氯磺酰的光化学和电化学反应的应用

Scheme 20. Photochemical and electrochemical reaction applications of fluorochlorosulfonyls

图式21. 基于IMSF试剂的光催化反应合成策略

Scheme 21. Photocatalytic reaction synthesis strategy based on IMSF reagents

图式22. 基于IMSF试剂合成磺酰氟硼化物策略

Scheme 22. Strategies for the synthesis of sulfonyl fluoroborides based on IMSF reagents

图式23. 基于FABI试剂的光化学合成策略

Scheme 23. Photochemical synthesis strategies based on FABI reagents

图式24. 早期NF3的活化模式

Scheme 24. Previous activation modes of NF3

图式25. 基于NF3合成全氟胺类化合物策略

Scheme 25. Strategy for the synthesis of perfluorinated amines based on NF3

图式26. NF3的多样转化

Scheme 26. Diverse transformations of NF3

图式27. 烯丙基醇的脱氧氟化反应

Scheme 27. Deoxyfluorination of allyl alcohols

图式28. 基于Pt配合物活化SF6策略

Scheme 28. SF6 activation strategy based on Pt complexes

图式29. 基于联吡啶类化合物活化SF6策略

Scheme 29. SF6 activation strategy based on bipyridines

图式30. 基于氮杂卡宾活化SF6策略

Scheme 30. SF6 activation strategy based on nitrogen carbene

图式31. 基于富电子膦配体活化SF6策略

Scheme 31. SF6 activation strategy based on nitrogen carbene

图式32. 基于吩噻嗪光催化活化SF6

Scheme 32. Photoredox Catalytic Activation of SF6 based on phenothiazine

图式33. 基于二苯甲酮光催化活化SF6

Scheme 33. Photoredox catalytic activation of SF6 based on benzophenone

图式34. 电化学策略活化SF6

Scheme 34. Electrochemical strategy to activate SF6

图式35. 基于TDAE-SF5-F试剂实现的多功能转化

Scheme 35. Multifunctional conversion based on TDAE-SF5-F reagent

图式36. SF5Cl参与的不饱和键加成反应

Scheme 36. Unsaturated bond addition reactions involving SF5Cl

图式37. SF5Cl与重氮化合物选择性构建α-SF5羰基化合物

Scheme 37. Selective construction of α-SF5 carbonyl compounds by SF5Cl and diazo compounds

图式38. SF5Cl、重氮化合物、烯烃参与的三组分反应

Scheme 38. Three-component reaction involving SF5Cl, diazo compounds and alkenes

图式39. 基于TDAE-SF5-F试剂实现的多功能转化

Scheme 39. Multifunctional conversion based on TDAE-SF5-F reagent

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关于惰性含氟温室气体转化与利用的研究进展

Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases

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