Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (6): 1184-1196.DOI: 10.6023/cjoc201512017 Previous Articles     Next Articles



傅颖, 赵兴玲, 侯博   

  1. 西北师范大学化学化工学院兰州 730070
  • 收稿日期:2015-12-11 修回日期:2016-01-11 发布日期:2016-02-02
  • 通讯作者: 傅颖
  • 基金资助:


Progress on the Sulfonylation and Desulfonylative Reactions of Sulfonyl Chlorides

Fu Ying, Zhao Xingling, Hou Bo   

  1. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070
  • Received:2015-12-11 Revised:2016-01-11 Published:2016-02-02
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21262030, 20962017).

Being an active class of electrophiles, the desulfitative cross-couplings of sulfonyl chlorides has emerged as a hot issue nowadays. Under suitable temperature and transitional metal catalysis, sulfonyl chlorides efficiently cross-coupled with a wide range of nucleophiles which were potential in several important organic synthesis. The transitional metal catalyzed desulfitative coupling reactions of sulfonyl chlorides are briefly reviewed and are compared with their corresponding sulfonylation reaction in order to find the key factors that determine desulfonation and further providing reliable proposal for future researches.

Key words: sulfonyl chloride, cross-coupling reaction, desulfitative