Recent Advances in the C(sp2)-S Bond Formation Reactions by Transition Metal-Free C(sp2)-H Functionalization

doi:10.6023/cjoc201702009

Abstract

Aryl/vinyl thioethers containing C(sp²)-S bonds are prevalent in biologically relevant molecules and compounds with other potential applications. Around the past decade, rapid progress has taken place in the research area of C(sp²)-S construction, and a large number of efficient new catalytic systems as well as structurally versatile substrates have been identified for such reactions, which significantly enriched the content of the synthetic methodologies on C(sp²)-S bond formation. This review introduces mainly the research advances on transition metal-free C(sp²)-S bond forming reaction by means of C(sp²)-H bond functionalization over the period of 2001~2016.

Key words: transition metal-free, C(sp²)-H bond, (Hetero)aryl, vinyl, C(sp²)-S bond formation

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Liu Yunyun, Xiong Jin, Wei Li. Recent Advances in the C(sp²)-S Bond Formation Reactions by Transition Metal-Free C(sp²)-H Functionalization[J]. Chin. J. Org. Chem., 2017, 37(7): 1667-1680.

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无过渡金属催化的C(sp²)-H键官能化反应构建C(sp²)-S键研究进展

Recent Advances in the C(sp²)-S Bond Formation Reactions by Transition Metal-Free C(sp²)-H Functionalization

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无过渡金属催化的C(sp2)-H键官能化反应构建C(sp2)-S键研究进展