Supramolecular Self-Assembly between Teteamethyl Cucurbit[6]uril and Alkyl Viologens

doi:10.6023/cjoc201702023

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (8): 2022-2027.DOI: 10.6023/cjoc201702023 Previous Articles Next Articles

ARTICLE

对称四甲基六元瓜环与紫精类化合物的超分子自组装

白东^a, 王鑫^b, 高中政^a, 邱胜超^a, 陶朱^a, 张建新^c, 肖昕^a

a 贵州省大环化学及超分子化学重点实验室贵州大学贵阳 550025;
b 安阳工学院化学与环境工程学院安阳 455000;
c 贵州省天然产物化学重点实验室贵阳 550025

收稿日期:2017-02-18 修回日期:2017-02-18 发布日期:2017-04-21
通讯作者: 肖昕 E-mail:gyhxxiaoxin@163.com
基金资助:
贵州省高层次创新型人才培养计划（No.2016-5657）和贵州省科学技术基金（Nos.2016-1030，2013-2150）资助项目.

Supramolecular Self-Assembly between Teteamethyl Cucurbit[6]uril and Alkyl Viologens

Bai Dong^a, Wang Xin^b, Gao Zhongzheng^a, Qiu Shengchao^a, Tao Zhu^a, Zhang Jianxin^c, Xiao Xin^a

a Key Laboratory of Macrocyclic and Supramolecular Chenmistry of Guizhou Province, Guizhou University, Guiyang 550025;
b College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang 455000;
c Key Laboratory of Chemistry for Natural Products of Guizhou Province, Guiyang 550025

Received:2017-02-18 Revised:2017-02-18 Published:2017-04-21
Contact: 10.6023/cjoc201702023 E-mail:gyhxxiaoxin@163.com
Supported by:
Project supported by the High-Level Talents of Guizhou Province (No. 2016-5657) and the Science and Technology Fund of Guizhou Province (Nos. 2016-1030, 2013-2150).

1. Supramolecular Self-Assembly between Teteamethyl Cucurbit[6]uril and Alkyl Viologens.PDF(902KB)

Abstract

Three symmetric viologen derivatives bearing aliphatic substituents of variable length were employed as guests, and the supramolecular self-assembly between teteamethyl cucurbit[6]uril (TMeQ[6]) and these viologen derivatives guests has been studied by ¹H NMR spectroscopy, electronic absorption spectroscopy, isothermal titration calorimetry, mass spectrometry and X-ray diffraction methods in details. The experimental results revealed that there are similar interaction models between TMeQ[6] and three viologens guest, the alkyl chains of the guests are located inside the cavity of the TMeQ[6] host, whereas the 4,4'-dipyridyl moieties of the guests remain outside of the portal, forming a 2:1 host-guest inclusion complex.

Key words: TMeQ[6], viologen derivatives, dumbbell shaped, supramolecular, self-assembly

Cite this article

Bai Dong, Wang Xin, Gao Zhongzheng, Qiu Shengchao, Tao Zhu, Zhang Jianxin, Xiao Xin. Supramolecular Self-Assembly between Teteamethyl Cucurbit[6]uril and Alkyl Viologens[J]. Chin. J. Org. Chem., 2017, 37(8): 2022-2027.

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对称四甲基六元瓜环与紫精类化合物的超分子自组装

Supramolecular Self-Assembly between Teteamethyl Cucurbit[6]uril and Alkyl Viologens

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