Synthesis,Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes

doi:10.6023/cjoc201704035

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (10): 2647-2654.DOI: 10.6023/cjoc201704035 Previous Articles Next Articles

ARTICLE

含嘧啶环的新型棒-线状N^C^N型二价铂配合物的合成及其自组装和荧光性能的表征

杨蕾^a,b, 胡杰娜^b, 曾旺^b, 吴洋^b, 李贤英^c, 张灯青^b, 金武松^b

a 上海市崇明县环境监测站上海 202150;
b 东华大学化学化工与生物工程学院上海 201620;
c 东华大学环境科学与工程学院上海 201620

收稿日期:2017-04-20 修回日期:2017-06-13 发布日期:2017-06-16
通讯作者: 李贤英, 金武松 E-mail:seanlee@dhu.edu.cn;wsjin@dhu.edu.cn
基金资助:
上海市科委科技创新行动计划基础研究（No.16JC1401900）资助项目.

Synthesis,Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes

Yang Lei^a,b, Hu Jiena^b, Zeng Wang^b, Wu Yang^b, Li Xianying^c, Zhang Dengqing^b, Jin Wusong^b

a Shanghai Chongming Environmental Monitoring Station, Shanghai 202150;
b College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620;
c College of Environmental Science and Engineering, Donghua University, Shanghai 201620

Received:2017-04-20 Revised:2017-06-13 Published:2017-06-16
Contact: 10.6023/cjoc201704035 E-mail:seanlee@dhu.edu.cn;wsjin@dhu.edu.cn
Supported by:
Project supported by the Science and Technology Commission of Shanghai Municipality (No.16JC1401900).

1. Synthesis,Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes.PDF(4168KB)

Abstract

Pyrimidine-contained novel rod-coil shaped N^C^N-type tridentate ligand 1 and its platinum(Ⅱ) complexe 1-Pt were synthesized, and their structures were characterized by NMR spectroscopy and MALDI-TOF mass spectrometry. The self-assembly and optical properties of 1-Pt were investigated with FE-SEM, UV-Vis and fluorescence spectroscopies. The result indicated that the unique rod-coil structure of 1-Pt enhanced intermolecular π-π stacking and showed excellent self-assembly performance in organic solvents which allowing for modulation of luminescence.

Key words: pyrimidine, rod-coil structure, platinum(Ⅱ) complex, self-assembly, fluorescence

Cite this article

Yang Lei, Hu Jiena, Zeng Wang, Wu Yang, Li Xianying, Zhang Dengqing, Jin Wusong. Synthesis,Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes[J]. Chin. J. Org. Chem., 2017, 37(10): 2647-2654.

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含嘧啶环的新型棒-线状N^C^N型二价铂配合物的合成及其自组装和荧光性能的表征

Synthesis,Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes

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