Catalytic Pyrolysis of Lignin for Directional Production of p-Xylene over Metal Oxides-Modified HZSM-5 Catalysts

doi:10.6023/cjoc201803039

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 2101-2108.DOI: 10.6023/cjoc201803039 Previous Articles Next Articles

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金属氧化物改性的HZSM-5催化热解木质素定向制备对二甲苯

贾启芳^a, 朱丽娟^a, 范明慧^b, 李全新^a

a 中国科学技术大学化学物理系安徽省生物质洁净能源重点实验室合肥 230026;
b 烟草化学安徽省重点实验室安徽中烟工业有限责任公司合肥 230088

收稿日期:2018-03-25 修回日期:2018-05-08 发布日期:2018-05-24
通讯作者: 李全新 E-mail:liqx@ustc.edu.cn
基金资助:
国家重点基础研究发展计划（973计划，No.2013CB228105）、长江学者和创新团队发展计划和中央高校基础科研基金（No.2060190040）资助项目.

Catalytic Pyrolysis of Lignin for Directional Production of p-Xylene over Metal Oxides-Modified HZSM-5 Catalysts

Jia Qifang^a, Zhu Lijuan^a, Fan Minghui^b, Li Quanxin^a

a Department of Chemical Physics, Anhui Key Laboratory of Biomass Clean Energy, University of Science and Technology of China, Hefei 230026;
b Anhui Key Laboratory of Tobacco Chemistry, Anhui Tobacco Industrial. Co., Ltd., Hefei 230088

Received:2018-03-25 Revised:2018-05-08 Published:2018-05-24
Contact: 10.6023/cjoc201803039 E-mail:liqx@ustc.edu.cn
Supported by:
Project supported by the National Key Basic Program of China (973 Program, No. 2013CB228105), the Program for Changjiang Scholars and Innovative Research Team in University and the Fundamental Research Funds for the Central Universities (No. 2060190040).

1. Catalytic Pyrolysis of Lignin for Directional Production of p-Xylene over Metal Oxides-Modified HZSM-5 Catalysts.PDF(194KB)

Abstract

Para-xylene (p-xylene) is an important bulk chemical in petrochemical industry, and the production of biomass-based p-xylene is of great significance in both academic and industrial arenas. This work proves the one step process for the production of p-xylene through the catalytic pyrolysis of lignin into the aromatic monomers, together with the alkylation of light aromatics and the isomerization of xylenes isomers into p-xylene over metal oxides-modified HZSM-5 catalysts. The modified catalysts by adding the La, Mg, Ce, and Zn elements into HZSM-5 promoted the alkylation of light aromatics (like benzene and toluene) into xylenes, and the isomerization of m-/o-xylenes to p-xylene, due to the modulations of the acid strength and the strong acid sites. Co-catalytic pyrolysis of lignin and methanol significantly enhanced the production of p-xylene during the catalytic pyrolysis of lignin. The highest p-xylene yield of 13.9% with a p-xylene/xylenes ratio of 82.7% was obtained by the co-catalytic pyrolysis of lignin with 33 wt% methanol over the 20% La₂O₃/HZSM-5 catalyst. The reaction pathway for the formation of p-xylene from lignin was addressed based on the identified products and the characterization of catalysts.

Key words: lignin, p-xylene, catalytic pyrolysis, alkylation, isomerization

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Jia Qifang, Zhu Lijuan, Fan Minghui, Li Quanxin. Catalytic Pyrolysis of Lignin for Directional Production of p-Xylene over Metal Oxides-Modified HZSM-5 Catalysts[J]. Chin. J. Org. Chem., 2018, 38(8): 2101-2108.

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金属氧化物改性的HZSM-5催化热解木质素定向制备对二甲苯

Catalytic Pyrolysis of Lignin for Directional Production of p-Xylene over Metal Oxides-Modified HZSM-5 Catalysts

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