New Application of β,γ-Unsaturated α-Ketoesters in Asymmetric Catalysis

doi:10.6023/cjoc202001019

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (6): 1448-1460.DOI: 10.6023/cjoc202001019 Previous Articles Next Articles

β,γ-不饱和α-酮酸酯在不对称催化中的应用

陈张鹏飞, 兰文捷, 余轩, 傅滨

中国农业大学理学院北京 100193

收稿日期:2020-01-13 修回日期:2020-03-14 发布日期:2020-03-31
通讯作者: 傅滨 E-mail:fubinchem@cau.edu.cn
基金资助:
国家自然科学基金（No.21572265）和科技部支撑计划（No.2015BAK45B01）资助项目.

New Application of β,γ-Unsaturated α-Ketoesters in Asymmetric Catalysis

ChenZhang Pengfei, Lan Wenjie, Yu Xuan, Fu Bin

College of Science, China Agricultural University, Beijing 100193

Received:2020-01-13 Revised:2020-03-14 Published:2020-03-31
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21572265) and the Ministry of Science and Technology of China (No. 2015BAK45B01).

β,γ-Unsaturated α-ketoester is a class of polyfunctional synthon. Due to its 1,2-dicarbonyl structure and multiple reactive sites, it has been used for the synthesis of various compounds. In the past twenty years, a number of chiral Lewis acid catalysts and organocatalysts have been applied to asymmetric catalytic reactions using β,γ-unsaturated α-ketoesters and various optically active compounds have been synthesized. The current progress of β,γ-unsaturated α-ketoesters in asymmetric catalysis according to the three different reaction sites, unsaturated acyl conjugate system, carbon-carbon double bond and carbonyl group, is summarized. Finally, the limitation of related reactions and the future development trends are also pointed out.

Key words: β,γ-unsaturated α-ketoester, asymmetric catalysis, application

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ChenZhang Pengfei, Lan Wenjie, Yu Xuan, Fu Bin. New Application of β,γ-Unsaturated α-Ketoesters in Asymmetric Catalysis[J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1448-1460.

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β,γ-不饱和α-酮酸酯在不对称催化中的应用

New Application of β,γ-Unsaturated α-Ketoesters in Asymmetric Catalysis

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