Chinese Journal of Organic Chemistry ›› 2019, Vol. 39 ›› Issue (11): 3040-3050.DOI: 10.6023/cjoc201904022 Previous Articles     Next Articles

新型光敏剂2, 4, 5, 6-四(9-咔唑基)间苯二腈在无金属有机光合成中的应用

陈锦杨*(), 李玉涵, 梅兰, 吴红谕   

  1. 长江师范学院化学化工学院 重庆涪陵 408000
  • 收稿日期:2019-04-09 发布日期:2019-07-24
  • 通讯作者: 陈锦杨
  • 基金资助:

Application of Photosensitizer 2, 4, 5, 6-Tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene in Photo-induced Transition-Metal-Free Organic Synthesis

Chen Jinyang*(), Li Yuhan, Mei Lan, Wu Hongyu   

  1. College of Chemistry and Chemical Engineering, Yangtze Normal University, Fuling, Chongqing 408000
  • Received:2019-04-09 Published:2019-07-24
  • Contact: Chen Jinyang
  • Supported by:
    the Basic and Frontier Research Project of Chongqing City(Cstc2018jcyjAX0051)

Visible-light-promoted organic synthesis is an important research hotspot and frontier in organic chemistry in recent years. Particularly, as a novel organic photosensitizer, 2, 4, 5, 6-tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene (4CzIPN) has showed excellent catalytic performance in visible-light-induced radical reactions. The recent progress on the transition-metal-free photosynthesis under visible-light catalyzed by 4CzIPN is reviewed, and the application of 4CzIPN for photocatalytic organic transformations from different precursors (including silicon reagent, carboxylic acid and its derivatives, sulfur-containing reagent and fluorine reagent) is included.

Key words: 2, 4, 5, 6-tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene (4CzIPN), organophotocatalyst, visible-light-induced, metal-free