Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (3): 563-574.DOI: 10.6023/cjoc201910031 Previous Articles     Next Articles

Special Issue: 有机光催化虚拟合辑


李祯龙a, 金健b, 黄莎华a,b   

  1. a 上海应用技术大学化学与环境工程学院 上海 201418;
    b 中国科学院上海有机化学研究所 中国科学院天然产物有机合成化学重点实验室 分子合成卓越创新中心 上海 200032
  • 收稿日期:2019-10-23 修回日期:2019-11-21 发布日期:2020-04-02
  • 通讯作者: 金健, 黄莎华;
  • 基金资助:

Recent Advances in Transition Metal-Catalyzed Cross-Coupling Reactions Directly Promoted by Visible Light

Li Zhenlonga, Jin Jianb, Huang Shahuaa,b   

  1. a School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418;
    b CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2019-10-23 Revised:2019-11-21 Published:2020-04-02
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21402121) and the Collaborative Innovation Program of Shanghai Institute of Technology (No. XTCX2015-16).

Over the last decades, the transition metal-catalyzed cross-coupling reactions have become powerful organic synthetic methods for forming carbon-carbon and carbon-heteroatom bonds. Very recently, the introduction of visible light into transition metal catalysis opened a new avenue for achieving novel, highly enabling cross-coupling reactions that otherwise were elusive. This type of reaction has received extensive attention due to its simple, mild conditions and no need of photocatalyst. Based on the classification of transition metals, the research progress of transition metal-catalyzed cross-coupling reactions directly promoted by visible light is reviewed.

Key words: visible light-promoted, transition metal-catalyzed, cross-coupling