γ-Aluminum Oxide-Mediated Iodination of Terminal Alkynes

doi:10.6023/cjoc202002014

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (7): 2153-2158.DOI: 10.6023/cjoc202002014 Previous Articles Next Articles

γ-三氧化二铝促进的炔烃碘代反应研究

姚明^a, 张静静^a,b, 杨森^a, 熊航行^a,b

a 荆楚理工学院化工与药学院湖北荆门 448000;
b 武汉工程大学化工与制药学院武汉 430205

收稿日期:2020-02-13 修回日期:2020-03-27 发布日期:2020-04-13
通讯作者: 姚明, 熊航行 E-mail:yaomingcep@jcut.edu.cn;731990153@qq.com
基金资助:
湖北省教育厅优秀中青年创新团队项目基金(No. T201719)资助项目.

γ-Aluminum Oxide-Mediated Iodination of Terminal Alkynes

Yao Ming^a, Zhang Jingjing^a,b, Yang Sen^a, Xiong Hangxing^a,b

a College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jingmen, Hubei 448000;
b School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205

Received:2020-02-13 Revised:2020-03-27 Published:2020-04-13
Supported by:
Project supported by the Science Technology Foundation for Creative Research Group of Hubei Department of Education (No. T201719).

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Abstract

A simple two-step, one-pot synthesis of 1,2,2-triiodovinyl derivatives from terminal alkynes using N-iodosuc-cinimide and iodine as precursors, activated with γ-aluminum oxide is developed. This approach resulted in moderate to excellent yields, good functional group tolerance and utilization of an inexpensive catalyst.

Key words: terminal alkyne, iodination, aluminum oxide, 1,2,2-triiodovinyl derivative, one-pot process

Cite this article

Yao Ming, Zhang Jingjing, Yang Sen, Xiong Hangxing. γ-Aluminum Oxide-Mediated Iodination of Terminal Alkynes[J]. Chinese Journal of Organic Chemistry, 2020, 40(7): 2153-2158.

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γ-三氧化二铝促进的炔烃碘代反应研究

γ-Aluminum Oxide-Mediated Iodination of Terminal Alkynes

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