Progress in Photocatalytic Hydrosilylation

doi:10.6023/cjoc202302031

Abstract

Organosilicon products have become an indispensable part of our lives today. Catalytic hydrosilylation reaction is one of the important methods for preparing organosilicon chemicals and materials. The research and development of inexpensive and excellent catalysts have received extensive attention. At present, the research on catalytic hydrosilylation mainly focuses on exploring the catalytic properties of new noble metal and non-precious metal complexes. However, due to the high cost of noble metals and the low catalytic activity of non-noble metal complexes, photocatalysis is an environmentally friendly and safe method. Catalytic methods and photocatalytic hydrosilylation reactions have received much attention. In this paper, the research progress of photocatalytic hydrosilylation in recent years is introduced.

Key words: hydrosilylation, photocatalysis, metal complexes, radical, photoinitiator

Cite this article

Jun Liu, Jiajian Peng, Ying Bai, Jiayun Li, Zijie Song, Peng Liu, Ting Ouyang, Huilin Lan. Progress in Photocatalytic Hydrosilylation[J]. Chinese Journal of Organic Chemistry, 2023, 43(10): 3558-3568.

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Fig. & Tab. 25

Scheme 1. Hydrosilylation reaction catalyzed by rhodium complex under light

Scheme 2. Reaction mechanism of hydrosilylation catalyzed by copper complex

Scheme 3. Mechanism of tetrabutylammonium deca-tungstic acid-catalyzed hydrosilylation reaction

Scheme 4. Mn2(CO)10 catalyzed hydrosilylation reaction of va- rious olefins with MDHM

Scheme 5. Iron-catalyzed reaction mechanism of triphenylsilane and benzyl acrylate

Scheme 6. Au nanocatalyzed silicon-catalyzed hydrosilylation reaction

Scheme 7. Photo driven transition metal catalyzed hydrosilylation addition reaction

Scheme 8. Diruthenium complex and its catalytic reaction mechanism

Scheme 9. Mn2(CO)10 catalyzed addition reaction of carbonyl compounds

Scheme 10. Illumination of carbonyl manganese catalyzed hydrosilylation reaction

Scheme 11. Photocatalytic addition reaction mechanism of hydrosilylation of conjugated dienes

Scheme 12. Synthesis of aminocarbene platinum complexes

Scheme 13. Mechanism of Mn2(CO)10-catalyzed hydrosilylation reaction

Scheme 14. 1,2,3,5-Tetracarbazole-4,6-dicyanobenzene photocatalytic system

Scheme 15. Photocatalytic hydrosilylation reaction to synthesize β-silicon α-amino acid

Scheme 16. Mechanism of photocatalytic hydrosilylation for synthesis of β-silicon α-amino acids

Scheme 17. Mechanism of photocatalytic hydrosilylation of octene and phenylsilane

Scheme 18. Photocatalytic hydrosilylation of 3-alkynyl acetate and tris(trimethylsilyl)silane

Scheme 19. Mechanism of photocatalytic hydrosilylation of alkynes

Scheme 20. Mechanism of eosin Y photocatalytic addition reaction of hydrosilylation

Scheme 21. Visible light-driven radical hydrosilation of allenes

Scheme 22. Photocatalytic radical cyclization of enyne compounds

Scheme 23. Visible light driven hydrosilylation of diene radical

Scheme 24. Photocatalytic hydrosilylation reaction on porous silicon surface

Scheme 25. Transition of photoactive compounds

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