Research Progress on Copper-Catalyzed Asymmetric Synthesis of Chiral Organophosphorus Compounds

doi:10.6023/cjoc202405002

Chinese Journal of Organic Chemistry

REVIEW

铜催化的手性膦化合物不对称合成研究进展

李晖^*,a, 殷亮^*,b

^a运城学院应用化学系运城 044000;
^b中国科学院上海有机化学研究所先进氟氮材料重点实验室上海 200032

收稿日期:2024-05-05 修回日期:2024-06-11
基金资助:
山西省高等学校科技创新(No. 2022L478), 山西省基础研究计划(No. 202303021211189)资助项目.

Research Progress on Copper-Catalyzed Asymmetric Synthesis of Chiral Organophosphorus Compounds

Hui Li^*,a, Liang Yin^*,b

^aDepartment of Applied Chemistry, Yuncheng University, Yuncheng, 044000;
^bKey Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

Received:2024-05-05 Revised:2024-06-11
Contact: *E-mail: lihuiwf@ycu.edu.cn; liangyin@sioc.ac.cn
Supported by:
Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (No. 2022L478), Natural Science Foundation of Shanxi province, China (No. 202303021211189).

Chiral organophosphorus compounds have a wide range of application in the fields of medicine, pesticides, and functional materials, and also serve as versatile ligands or organocatalysts in asymmetric catalysis. Therefore, their asymmetric synthesis has attracted an increasing attention from chemists and has become one hot research topic in recent years. Asymmetric P—C or P—N bond formation by using organophosphorus compounds bearing P—H bond and various electrophilic partners serves as a straightforward and powerful strategy for constructing chiral organophosphorus compounds. Recent progress in asymmetric synthesis of chiral organophosphorus compounds catalyzed by chiral copper complexes or copper/organocatalyst co-catalytic systems is summarized. P-chiral or/and backbone chiral organophosphorus compounds are obtained in these reactions. This paper is divided into two sections based on whether the valence state of copper is changed or not during the reaction process. Aside from the substrate scopes, the mechanisms and potential applications of some representative methodologies are also included.

Key words: copper catalysis, asymmetric synthesis, chiral organophosphorus compounds, P-chirality

Cite this article

Hui Li, Liang Yin. Research Progress on Copper-Catalyzed Asymmetric Synthesis of Chiral Organophosphorus Compounds[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202405002.

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铜催化的手性膦化合物不对称合成研究进展

Research Progress on Copper-Catalyzed Asymmetric Synthesis of Chiral Organophosphorus Compounds

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