Chinese Journal of Organic Chemistry 2024, 44(12)

- About the Cover:
  
  An organophosphoric acid catalyzed [3＋3] cycliza-tion of 2-arylidene-indan-1,3-diones with enaminones has been established by Guo, Yu, Wan, Lu, Tan, and Shi on page 3727, affording a series of structurally diverse indenoquinolinedione derivatives in overall high yields. This [3＋3] cyclization has some advantages such as mild reaction conditions, readily available catalyst and wide substrate range, which provides an efficient method for constructing biologically important 1,4-dihydro- pyridine motif.
- About the Cover:
  
  Phosphine-catalyzed [5＋1] annulation of Morita- Baylis-Hillman (MBH) carbonates with 1,3-dicarbonyl compounds was reported by Ren, Shi, Tang and Guo on page 3739. The reaction worked well under mild reaction conditions. This is the first time that MBH carbonates functioned as all-carbon five-membered syn- thon in phosphine catalysis.
- About the Cover:
  
  Phosphine chlorides (R¹R²PCl) and hydroxyl-containing compounds (RA—OH) can form a RA—O—PR¹R² intermediate, which undergoes A—O bond cleavage and A—P bond formation leading to P(III)→P(V) rear-rangement to form pentavalent organophosphorus com-pounds. The P(III)→P(V) rearrangement reactions of phosphine chlorides with different types of hydroxyl containing compounds for the synthesis of phosphine oxides, phosphonates, and phosphoric amides are re-viewed by Yang, Yi, Wu, Zhang, Bai, Li and Xu on page 3639.
- About the Cover:
  
  The desulfurization reaction of alkenyl sulfonium salts with phosphine oxides to form C(sp²)—P bonds was rea- lized under room temperature. This method shows good functional group compatibility, offering a straightforward and efficient preparation route for terminal vinyl phosphine oxides. More details can be found in the article by An, Lv, Sun, Chen, Qu, and Yu on page 3747.
2024, 44(12)

25 December 2024
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Research Progress on Copper-Catalyzed Asymmetric Synthesis of Chiral Organophosphorus Compounds

Hui Li, Liang Yin

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3575-3586 DOI: 10.6023/cjoc202405002

Abstract( 355) HTML( 39) PDF(766KB)( 558 )

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Research Progress in the Application of Supported Catalysts Containing Phosphine

Yongzhe Zhao, Xiangfei Kong, Junliang Zhang, Junfeng Yang

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3587-3608 DOI: 10.6023/cjoc202403016

Abstract( 273) HTML( 12) PDF(1338KB)( 382 )

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Progress in Synthesis of Medium-Sized Ring Compounds Catalyzed by Organophosphine

Xuling Pan, You Huang

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3609-3620 DOI: 10.6023/cjoc202405021

Abstract( 392) HTML( 10) PDF(717KB)( 578 )

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Recent Advances in the Synthesis of P-Stereogenic Compounds via Desymmetrization Strategy

Guotao Lin, Jian Xu, Qiuling Song

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3621-3638 DOI: 10.6023/cjoc202406029

Abstract( 397) HTML( 11) PDF(886KB)( 622 )

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Progress in the P(III)→P(V) Rearrangement Reaction of Phosphine Chlorides and Hydroxyl Containing Compounds

Lulu Yang, Cui Yi, Jiale Wu, Yuxuan Zhang, Meiqi Bai, Yang Li, Silong Xu

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3639-3646 DOI: 10.6023/cjoc202406052

Abstract( 241) HTML( 10) PDF(655KB)( 305 )

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Advances in Catalytic Asymmetric Hydrogen-Phosphine/Phosphorus Functionalization of Unsaturated Carbon-Carbon Bonds

Tingjia Sun, Guoyin Sun, Wei Sun, Xuesong Peng, Juan Liao, Yong You, Weicheng Yuan

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3647-3677 DOI: 10.6023/cjoc202405046

Abstract( 267) HTML( 11) PDF(1254KB)( 454 )

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Advances in Mechanistic Studies of Metal-Catalyzed Hydrophosphinylation of Non-Activated Alkynes

Yi-Yu Liu, Yudong Hu, Qing-Wei Zhang

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3678-3685 DOI: 10.6023/cjoc202405019

Abstract( 148) HTML( 6) PDF(569KB)( 101 )

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Recent Advances on the Synthesis and Application of α,α-Difluoro-β-aminophosphonates

Youlong Du, Qian Wang, Haibo Mei, Romana Pajkert, Gerd-Volker Röschenthaler, Jianlin Han

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3686-3701 DOI: 10.6023/cjoc202405013

Abstract( 198) HTML( 5) PDF(816KB)( 240 )

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Advances in Organic Reactions Using Phosphorus Acid as Reducing Agent

Jing Xiao, Yuxiang Xie, Libiao Han

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3702-3712 DOI: 10.6023/cjoc202404015

Abstract( 262) HTML( 6) PDF(701KB)( 345 )

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ARTICLE

Copper Mediated sp³-C—N Bond Cleavage for Synthesizing (Diarylmethyl)diarylphosphine Oxides

Jianyu Dong, Jie Huo, Ying Guo, Dan Zhou, Yongbo Zhou

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3713-3719 DOI: 10.6023/cjoc202405051

Abstract( 166) HTML( 11) PDF(550KB)( 147 )

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Synthesis of a Sitagliptin Intermediate via Ruthenium-Catalyzed Asymmetric Hydrogenation of Enamine Ester

Yiwen Lü, Haihua Liao, Wenjun Tang

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3720-3726 DOI: 10.6023/cjoc202408013

Abstract( 233) HTML( 5) PDF(597KB)( 326 )

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Organophosphoric Acid Catalyzed [3＋3] Cyclization for the Synthesis of Indenoquinolinedione Derivatives

Xinyan Guo, Haolei Yu, Honglin Wan, Yu Lu, Wei Tan, Feng Shi

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3727-3738 DOI: 10.6023/cjoc202405040

Abstract( 205) HTML( 3) PDF(755KB)( 236 )

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Phosphine-Catalyzed [5＋1] Annulation of Morita-Baylis-Hillman Carbonates with 1,3-Dicarbonyl Compounds

Yue Ren, Wangyu Shi, Yi Tang, Hongchao Guo

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3739-3746 DOI: 10.6023/cjoc202405039

Abstract( 130) HTML( 0) PDF(567KB)( 181 )

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Synthesis of Terminal Vinyl Phosphine Oxides via Desulfonative C—P Formation from Alkenyl Sulfonium Salts

Jiangzhen An, Qiyan Lv, Kai Sun, Xiaolan Chen, Lingbo Qu, Bing Yu

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3747-3752 DOI: 10.6023/cjoc202405043

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Reactions of Alkynyl Aryl Phosphine Oxide with Oxalyl Bromide

Peng Zhao, Zhenjie Gan, Zhuo Li, Lili Wang, Zheng Duan

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3753-3760 DOI: 10.6023/cjoc202405014

Abstract( 181) HTML( 4) PDF(757KB)( 104 )

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Palladium/Phosphine Complex Catalyzed [4＋4] Annulations of Morita-Baylis-Hillman Carbonates and 1-Azadienes

Bo Zhu, Yang Yang, Qiyin Liu, Wei Du, Yingchun Chen

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3761-3770 DOI: 10.6023/cjoc202405020

Abstract( 219) HTML( 2) PDF(527KB)( 219 )

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Efficient Construction of Chiral Binaphthalene-Core Phosphepine Compounds Using Palladium-Catalyzed C—P Coupling Reactions

Cuiying Wang, Ying Zhang, Jia-Lian Zheng, Jia Yuan, Sixuan Meng, Jian Chen, Guang-Ao Yu

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3771-3783 DOI: 10.6023/cjoc202404004

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HIGHLIGHT

Axial Ligand Enabled Synthesis of Allenylsilane through Dirhodium(II) Catalysis

Liqun Yang, Zhaoguo Zhang

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3784-3785 DOI: 10.6023/cjoc202400059

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Strategic Application of Ynol-Diene Cyclization in the Total Synthesis of 17-nor-Cephalotane Diterpenoids

Zhi-Hua Ma, Yu-Ming Zhao

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3786-3787 DOI: 10.6023/cjoc202400060

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Stereospecific Sulfation of Organoboron Compounds

Xueying Chen, Guoyin Yin

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3788-3789 DOI: 10.6023/cjoc202400061

Abstract( 71) HTML( 4) PDF(416KB)( 112 )

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Bifunctional Iron-Catalyzed Alkyne Hydroalkylation for Construction of Stereoselective Alkene

Cui Xin, Wei-Min He

Chinese Journal of Organic Chemistry 2024, 44 (12), pp 3790-3792 DOI: 10.6023/cjoc202400062

Abstract( 77) HTML( 4) PDF(481KB)( 95 )

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