Design of Photoactive Cr- and Co-Based Complexes and Their Applications in Organic Synthesis

doi:10.6023/cjoc202512031

Chinese Journal of Organic Chemistry ›› 2026, Vol. 46 ›› Issue (4): 1513-1528.DOI: 10.6023/cjoc202512031 Previous Articles Next Articles

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具有光活性的铬、钴配合物的设计及其在有机合成中的应用进展

孟令旭^a, 申霖^a, 罗祥玲^a, 林玉妹^a^,^*(), 龚磊^a^,^b^,^*()

^a 厦门大学化学化工学院福建厦门 361005
^b 福建省能源材料科学与技术创新实验室(IKKEM) 福建厦门 361005

收稿日期:2025-12-22 修回日期:2026-02-02 发布日期:2026-03-06
通讯作者: 林玉妹, 龚磊
基金资助:
国家自然科学基金(22371237); 国家自然科学基金(22571265); 国家自然科学基金(22571263); 福建省自然科学基金(2024J010002); 及大学生创新创业训练计划(202510384058); 及大学生创新创业训练计划(2025X803)

Design of Photoactive Cr- and Co-Based Complexes and Their Applications in Organic Synthesis

Lingxu Meng^a, Lin Shen^a, Xiangling Luo^a, Yumei Lin^a^,^*(), Lei Gong^a^,^b^,^*()

^a College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005
^b Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian 361005

Received:2025-12-22 Revised:2026-02-02 Published:2026-03-06
Contact: Yumei Lin, Lei Gong
Supported by:
National Natural Science Foundation of China(22371237); National Natural Science Foundation of China(22571265); National Natural Science Foundation of China(22571263); Natural Science Foundation of Fujian Province(2024J010002); College Students’ Innovative Entrepreneurial Training Plan(202510384058); College Students’ Innovative Entrepreneurial Training Plan(2025X803)

Visible-light photocatalysis has become a powerful method for constructing structurally diverse organic molecules. Currently, metal-based photocatalysts are predominantly rely on noble-metal complexes of iridium and ruthenium. In contrast, chromium and cobalt offer advantages of earth abundance and low cost, and their complexes, featuring tunable coordination environments and rich redox properties, have shown promising potential in photocatalytic organic synthesis. The structural design of photoactive Cr- and Co-based complexes and their applications in various organic transformations are systematically summarized, and the current challenges and future perspectives in this field are briefly discussed.

Key words: visible-light photocatalysis, photoredox catalysis, chromium complex, cobalt complex, catalytic organic synthesis

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Lingxu Meng, Lin Shen, Xiangling Luo, Yumei Lin, Lei Gong. Design of Photoactive Cr- and Co-Based Complexes and Their Applications in Organic Synthesis[J]. Chinese Journal of Organic Chemistry, 2026, 46(4): 1513-1528.

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Fig. & Tab. 14

Figure 1. Ligand design strategies for regulating the performance of photoactive complexes

Figure 2. Photophysical and electrochemical properties of chromium complexes with bipyridine and phenanthroline ligands

Figure 3. Photophysical and electrochemical properties of chromium complexes with isocyanide ligands

Scheme 1. Photooxidizing [Cr(Ph2phen)3](BF4)3 for promoting radical cation cycloadditions

Scheme 2. Photooxidizing [Cr(Ph2phen)3](BF4)3 for [4＋2] cycloaddition reactions of dienes with electron-deficient olefins

Scheme 3. Radical cation cyclopropanations via [Cr(Ph2phen)3](BF4)3

Scheme 4. Radical cation cyclopropanations via [Cr(Ph2phen)3](BF4)3

Scheme 5. Dearomative [3＋2] cycloadditions between indoles and vinyldiazo species

Scheme 6. Visible light-induced oxidative C—H bond cyanogenation and photochemically promoted aza-Diels-Alder-type reaction

Scheme 7. Visible-light mediated fixation of SO2 into sulfones or sulfonamides with Cr(III) photocatalysts

Figure 4. Photophysical and electrochemical properties of cobalt complexes

Scheme 8. Photocatalytic trifluoromethylation of polycyclic aromatic hydrocarbons

Scheme 9. Cobalt photocatalyzed C(sp2)—N cross-coupling of aryl amides and aryl boronic acids

Scheme 10. Cobalt photocatalyzed coupling reaction of aryl halides with pyrroles

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具有光活性的铬、钴配合物的设计及其在有机合成中的应用进展

Design of Photoactive Cr- and Co-Based Complexes and Their Applications in Organic Synthesis

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