The application of carbene reactive intermediates in organic synthesis I. New route for the synthesis of leaf alcohol

Chin. J. Org. Chem. ›› 1986, Vol. 6 ›› Issue (5): 360-362. Previous Articles Next Articles

卡宾活性中间体在有机合成中的应用I.合成叶醇的新路线

吴世晖;陶凤岗;甘耀东;许临晓

复旦大学化学系

发布日期:1986-10-25

The application of carbene reactive intermediates in organic synthesis I. New route for the synthesis of leaf alcohol

WU SHIHUI;TAO FENGGANG;GAN YAODONG;XU LINXIAO

Published:1986-10-25

Abstract

EtCH:CCl2 was treated with BuLi in Et2O to give 1-butyne via an unsatd. carbene intermediate. Lithiation of 1-butyne followed by treatment with ethylene oxide gave 3-hexyn-1-ol, hydrogenation of which gave the title alcohol, cis-3-hexen-1-ol.

Key words: CARBENE, PERFUMES, BUTYLLITHIUM, ORGANIC SYNTHESIS, ENOLS, CHLOROPROPENES P, ETHYLENE OXIDE

CLC Number:

TQ65

Cite this article

WU SHIHUI;TAO FENGGANG;GAN YAODONG;XU LINXIAO. The application of carbene reactive intermediates in organic synthesis I. New route for the synthesis of leaf alcohol[J]. Chin. J. Org. Chem., 1986, 6(5): 360-362.

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卡宾活性中间体在有机合成中的应用I.合成叶醇的新路线

The application of carbene reactive intermediates in organic synthesis I. New route for the synthesis of leaf alcohol

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