Osmium tetroxide oxidation of cyclic allylic alcohols

Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (1): 38-40. Previous Articles Next Articles

Original Articles

环烯丙醇的四氧化锇氧化反应

刘志煜;许义斌;吴泽民;卢立晃;杨继英

中国科学院上海有机化学研究所

发布日期:1990-02-25

Osmium tetroxide oxidation of cyclic allylic alcohols

LIU ZHIYU;XU YIBIN;WU ZEMIN;LU LIHUANG;YANG JIYING

Published:1990-02-25

Abstract

Oxidation of cyclic allylic alcs. with osmium tetroxide was described. E.g., stirring alcohol I (Z = H, OH) with osmium tetroxide, and N-methylmorpholine N-oxide in pyridine at room temperature for 3 days gave 91% ketone I (Z = O).

Key words: ALCOHOL, OXIDATION, CARBONYL COMPOUNDS, CYCLOALKENE, PROPANOL P, STERIC EFFECT, OSMIUM OXIDE

CLC Number:

O621

Cite this article

LIU ZHIYU;XU YIBIN;WU ZEMIN;LU LIHUANG;YANG JIYING. Osmium tetroxide oxidation of cyclic allylic alcohols[J]. Chin. J. Org. Chem., 1990, 10(1): 38-40.

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环烯丙醇的四氧化锇氧化反应

Osmium tetroxide oxidation of cyclic allylic alcohols

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