Study on the interaction between β-cyclodextrin and low molecular aliphatic alcohol in aqueous solution with phenolphthatein as probe

Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (5): 432-435. Previous Articles Next Articles

Original Articles

酚酞作为探针研究水溶液中β-环糊精与低分子脂肪醇的互相作用

童林荟;刘育

中国科学院兰州化学物理研究所

发布日期:1990-10-25

Study on the interaction between β-cyclodextrin and low molecular aliphatic alcohol in aqueous solution with phenolphthatein as probe

TONG LINHUI;LIU YU

Published:1990-10-25

Abstract

It has been proved that in alkaline solution the three Ph groups of phenolphthalein (PP2-) have different polarity and the formation of the complex b-CD-PP2- had 1:1 stoichiometry. The cavity in b-CD was studied by using PP2- as probe. The binding constant of b-CD with aliphatic alcohol was determine by competitive inclusion method. The experimental results indicated that the cavity is an enzyme-like hydrophobic microenvironment.

Key words: AQUEOUS SOLUTION, ULTRAVIOLET SPECTROPHOTOMETRY, THERMODYNAMIC PROPERTIES, PROBES, PHENOLPHTHALEINUM, CYCLODEXTRIN, ELEMENTAL ANALYSIS, HYDROPHOBIC PROPERTIES, ALIPHATIC ALCOHOLS

CLC Number:

O621.16

Cite this article

TONG LINHUI;LIU YU. Study on the interaction between β-cyclodextrin and low molecular aliphatic alcohol in aqueous solution with phenolphthatein as probe[J]. Chin. J. Org. Chem., 1990, 10(5): 432-435.

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酚酞作为探针研究水溶液中β-环糊精与低分子脂肪醇的互相作用

Study on the interaction between β-cyclodextrin and low molecular aliphatic alcohol in aqueous solution with phenolphthatein as probe

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