Syntheses of iso-condensed heteroaromatic pyrroles and the application to the total syntheses of natural products

Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (2): 162-165. Previous Articles Next Articles

Original Articles

芳香杂环并吡咯的合成和在天然产物全合成中的应用

沙晋康;蔡琮莹

台湾清华大学化学系

发布日期:1993-04-25

Syntheses of iso-condensed heteroaromatic pyrroles and the application to the total syntheses of natural products

SHA JINKANG;CAI CONGYING

Published:1993-04-25

Abstract

A novel method, namely the intramolecular 1,3-dipolar cycloaddition and cycloreversion of azido-alkylidene malonates, for the preparation of iso-condensed heteroaromatic pyrroles has been developed. The application of this methos for the synthesis of 2,4-dihydropyrrolo[3,4-b]indole ring system, as well as the application of this ring system for the total syntheses of ellipticine alkaloids are reported.

Key words: AZIDE, ALKALOID, NATURAL PRODUCTS, CYCLOADDITION REACTION, TOTAL SYNTHESIS, ALKYLIDENE, MALONIC ESTER

CLC Number:

O629

Cite this article

SHA JINKANG;CAI CONGYING. Syntheses of iso-condensed heteroaromatic pyrroles and the application to the total syntheses of natural products[J]. Chin. J. Org. Chem., 1993, 13(2): 162-165.

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芳香杂环并吡咯的合成和在天然产物全合成中的应用

Syntheses of iso-condensed heteroaromatic pyrroles and the application to the total syntheses of natural products

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