Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (1): 95-99. Previous Articles     Next Articles

Original Articles

锌和锡参与下末端环氧化物的选择性烯丙基化反应

邓道利;陆忠辉   

  1. 中国科学院上海有机化学研究所;中国科学院上海有机化学研究所
  • 发布日期:1995-02-25

Zinc- and tin-mediated selective allylation of terminal epoxides

DENG DAOLI   

  • Published:1995-02-25

Allylation of terminal epoxides 1 can be carried out successfully by allyl bromide and metallic zinc or tin in a novel one-pot synthesis to give the homoallylic alcohols 2 and bishomoallylic alcohlos 3. The effect of substituents on epoxides was studied. The reaction pathway of this allylation was also suggested.

Key words: ZINC, TIN, EPOXIDE, ALLYLATION

CLC Number: