Aldol reactions of α-bromoketones with carbonyl compounds promoted by aluminum triiodide

Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (4): 319-323. Previous Articles Next Articles

Original Articles

三碘化铝促进的α-溴代酮与羰基化合物的Aldol反应

张世军

山东枣庄师范专科学校

发布日期:1997-08-25

Aldol reactions of α-bromoketones with carbonyl compounds promoted by aluminum triiodide

ZHANG SHIJUN

Published:1997-08-25

Abstract

α-Bromoketones reacted with carbonyl compounds to yield only β-hydroxyketones in moderate to high yields promoted by aluminum triiodide, prepared from metallic aluminum and iodime in situ in tetrahedronfuran at room temperature, and the reaction showed high syn selectivity.

Key words: ALUMINIUM, KETONE P, ACID CATALYST, HYDROXYL COMPOUNDS, STEREOSELECTIVITY, LEWIS ACID, IODIDE, CARBONYL COMPOUNDS, KETONE P, BROMOHYDROCARBON

CLC Number:

O621

Cite this article

ZHANG SHIJUN. Aldol reactions of α-bromoketones with carbonyl compounds promoted by aluminum triiodide[J]. Chin. J. Org. Chem., 1997, 17(4): 319-323.

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三碘化铝促进的α-溴代酮与羰基化合物的Aldol反应

Aldol reactions of α-bromoketones with carbonyl compounds promoted by aluminum triiodide

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