Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (05): 694-697. Previous Articles     Next Articles

Original Articles

氯代膦烯化合物与零价钯的氧化加成反应机理探讨

梁洪泽*,王强   

  1. (宁波大学材料科学与化学工程学院 宁波市新型功能材料及其制备科学实验室-
    省部共建国家重点试验室培育基地 宁波 315211)
  • 收稿日期:2005-08-03 修回日期:2006-02-20 发布日期:2006-04-28
  • 通讯作者: 梁洪泽

Investigation of Mechanism in the Oxidative Addition Reaction of Zerovalent Palladium to Chloro-substituted Phosphaalkene

LIANG Hong-Ze*,WANG Qiang   

  1. (State Key Laboratory Base of Novel Functional Materials and Preparation Science at Ningbo, Faculty of Materials Science and Chemical Engniecxing, Ningbo University, Ningbo 315211)
  • Received:2005-08-03 Revised:2006-02-20 Published:2006-04-28
  • Contact: LIANG Hong-Ze

On the contrary to the vinyl and aryl chlorides, the oxidative addition reaction of zerovalent palladium to chloro-substituted phosphaalkenes proceeded smoothly under mild conditions. The reaction pathway and the structure of final products were found to depend on the structure of starting materials and the mechanism was proposed.

Key words: oxidative addition, palladium complex, halogen-substituted phosphaalkene