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Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (05): 698-701. Previous Articles     Next Articles

Reports

在离子液体中4-芳基-5-氧代-1,4,5,6,7,8-六氢喹啉-3-羧酸酯的合成

杜百祥，李玉玲，王香善*， 张梅梅，史达清，屠树江   

  1. (徐州师范大学化学系 江苏省药用植物生物技术重点实验室 徐州 221116)
  • 收稿日期:2005-07-11 修回日期:2005-11-04 发布日期:2006-04-28
  • 通讯作者: 杨光富

Synthesis of 4-Aryl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate in Ionic Liquid

DU Bai-Xiang,LI Yu-Ling,WANG Xiang-Shan*,ZHANG Mei-Mei
SHI Da-Qing,TU Shu-Jiang   

  1. (Department of Chemistry, Xuzhou Normal University, The Key Laboratory of Biotechnology on
    Medical Plant of Jiangsu Province, Xuzhou 221116)
  • Received:2005-07-11 Revised:2005-11-04 Published:2006-04-28
  • Contact: YANG Guang-Fu

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4-Aryl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylates were synthesized by the reaction of aromatic aldehydes, 5,5-dimethyl-1,3-cyclohexanedione or 1,3-cyclohexanedione and 2-aminocroto- nate in ionic liquid [bmimBF4]. Compared with the previous methods, this new method has the advantages of high yields and environmental benignity. The structure of products was characterized by IR, 1H NMR spectra and elemental analyses, and further confirmed by X-ray analysis.

Key words: hexahydroquinoline, synthesis, green chemistry, ionic liquid